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The subsequent treatment with HCl furnishes chloro(pentafluoroethyl)plumbanes. The synthesis of the tris(pentafluoroethyl)plumbate(II) anion is facilitated by treatment of Pb(C\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    Cl with PPh\n                    <jats:sub>3<\/jats:sub>\n                    . In addition, formation of Pb(C\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    is achieved starting from Pb(OAc)\n                    <jats:sub>4<\/jats:sub>\n                    and is fully characterized by multinuclear NMR spectroscopy and by single crystal x\u2010ray diffraction of the 1,10\u2010phenanthroline adduct.\n                  <\/jats:p>","DOI":"10.1002\/chem.71402","type":"journal-article","created":{"date-parts":[[2026,7,18]],"date-time":"2026-07-18T15:52:01Z","timestamp":1784389921000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV"],"prefix":"10.1002","volume":"32","author":[{"given":"Michael","family":"Grasse","sequence":"first","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie Centrum f\u00fcr Molekulare Materialien Universit\u00e4t Bielefeld  Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lukas","family":"Hartmann","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie Centrum f\u00fcr Molekulare Materialien Universit\u00e4t Bielefeld  Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beate","family":"Neumann","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie Centrum f\u00fcr Molekulare Materialien Universit\u00e4t Bielefeld  Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hans\u2010Georg","family":"Stammler","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie Centrum f\u00fcr Molekulare Materialien Universit\u00e4t Bielefeld  Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9610-8478","authenticated-orcid":false,"given":"Berthold","family":"Hoge","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie Centrum f\u00fcr Molekulare Materialien Universit\u00e4t Bielefeld  Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,18]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/om030245v"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/om030621b"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature12340"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u2010328X(92)88006\u20105"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u2010328X(94)85011\u20109"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00304a038"},{"key":"e_1_2_7_8_1","unstructured":"H. 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