{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T16:14:19Z","timestamp":1783700059980,"version":"3.55.0"},"reference-count":96,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T00:00:00Z","timestamp":1783641600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T00:00:00Z","timestamp":1783641600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100009375","name":"Graduate School, Technische Universit\u00e4t M\u00fcnchen","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009375","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The chemistry of single\u2010site platinum surface complexes with phosphine ligands is rarely understood, in contrast to its well\u2010known chemistry in solution. This report describes the synthesis of a supported bis(phosphine)methylplatinum(II) complex on silicon dioxide (PtMe(PMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \/SiO\n                    <jats:sub>2<\/jats:sub>\n                    ) and its reactivity with carbon monoxide, hydrogen, and under inert gas. The parent compound and reaction intermediates are characterized by IR\u2010, solid\u2010state NMR, and X\u2010ray absorption spectroscopy. The sterically non\u2010demanding monodentate phosphine ligands stabilize the platinum centers, allowing the formation of several isolated\n                    <jats:italic>trans<\/jats:italic>\n                    complexes on silica. One of them is a platinum hydride that effectively catalyzes the isomerization of 1\u2010hexene. The stabilization of the molecular hydride contrasts with the reactivity of known supported platinum methyl complexes, such as PtMe(cod)\/SiO\n                    <jats:sub>2<\/jats:sub>\n                    , which tend to form supported platinum nanoparticles under the applied mild conditions.\n                  <\/jats:p>","DOI":"10.1002\/chem.71409","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T15:26:45Z","timestamp":1783697205000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Silica\u2010Supported Mononuclear Methyl\u2010Platinum Complexes Stabilized by Trimethylphosphine\u2014Synthesis, Structure, and Reactions Under Reducing Conditions"],"prefix":"10.1002","author":[{"given":"Lea S.","family":"Kopietz","sequence":"first","affiliation":[{"name":"Department of Chemistry, TUM School of Natural Sciences, and Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sven","family":"Schaefer","sequence":"additional","affiliation":[{"name":"Department of Chemistry RPTU Kaiserslautern\u2010Landau  Kaiserslautern Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oksana","family":"Storcheva","sequence":"additional","affiliation":[{"name":"Department of Chemistry, TUM School of Natural Sciences, and Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gabriele","family":"Raudaschl\u2010Sieber","sequence":"additional","affiliation":[{"name":"Department of Chemistry, TUM School of Natural Sciences, and Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Johannes","family":"Bitzer","sequence":"additional","affiliation":[{"name":"Department of Chemistry RPTU Kaiserslautern\u2010Landau  Kaiserslautern Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wolfgang","family":"Kleist","sequence":"additional","affiliation":[{"name":"Department of Chemistry RPTU Kaiserslautern\u2010Landau  Kaiserslautern Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3008-7875","authenticated-orcid":false,"given":"Klaus","family":"K\u00f6hler","sequence":"additional","affiliation":[{"name":"Department of Chemistry, TUM School of Natural Sciences, and Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,10]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"crossref","first-page":"6666","DOI":"10.1039\/D1CY01216A","article-title":"Transformation of Atomically Dispersed Platinum in SAPO\u201037 Into Platinum Clusters: Catalyst for Ethylene Hydrogenation","volume":"11","author":"Perez\u2010Aguilar J. 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