{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,18]],"date-time":"2026-07-18T17:02:42Z","timestamp":1784394162659,"version":"3.55.0"},"reference-count":75,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,7,18]],"date-time":"2026-07-18T00:00:00Z","timestamp":1784332800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,18]],"date-time":"2026-07-18T00:00:00Z","timestamp":1784332800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Dissipative self\u2010assembly in living systems relies on continuous fuel consumption and metabolic removal of waste to maintain non\u2010equilibrium structures. In contrast, most synthetic chemically fueled assemblies accumulate stoichiometric waste, limiting sustainability and repeatability. We report a waste\u2010free, chemically activated dissipative supramolecular gelation strategy enabled by a volatile gaseous activator. Ammonia transiently activates 12\u2010hydroxystearic acid (HSA) through reversible salt formation, converting HSA from a non\u2010assembling OFF state to a self\u2010assembling ON state in polar organic solvents where gelation is otherwise inaccessible. The resulting gels form rapidly, at markedly reduced minimum gelation concentrations, and exhibit tunable lifetimes governed by ammonia dissipation. Multimodal analyses (\n                    <jats:sup>1<\/jats:sup>\n                    H NMR, FTIR, and PXRD) reveal that salt\u2010formation and reinforced hydrogen bonding reorganize lamellar packing, leading to expanded interlayer spacing and cooperative supramolecular assembly. Open systems operate in a true dissipative regime, where continuous ammonia supply maintains the assembled state, while closed systems stabilize the gel through dynamic equilibrium with ammonia. Repeated pulsed ammonia charging and dissipation enable reversible gel\u2013sol cycling without accumulation of persistent chemical waste. This work establishes volatile\u2010activator\u2010driven gelation as a waste\u2010free platform for non\u2010equilibrium supramolecular materials and provides a blueprint for designing chemically activated soft matter systems that more closely emulate the sustainability of biological dissipative assemblies.\n                  <\/jats:p>","DOI":"10.1002\/chem.71424","type":"journal-article","created":{"date-parts":[[2026,7,18]],"date-time":"2026-07-18T16:07:37Z","timestamp":1784390857000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Volatile Chemical Activator Enables Waste\u2010Free Dissipative Supramolecular Assembly"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8416-9764","authenticated-orcid":false,"given":"Cijil","family":"Raju","sequence":"first","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram Thiruvananthapuram Kerala India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-8896-5250","authenticated-orcid":false,"given":"Aniruddha","family":"Mandal","sequence":"additional","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram Thiruvananthapuram Kerala India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sangeeth","family":"Sivasoudham","sequence":"additional","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram Thiruvananthapuram Kerala India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4005-3655","authenticated-orcid":false,"given":"Kana M.","family":"Sureshan","sequence":"additional","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram Thiruvananthapuram Kerala India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,18]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"crossref","first-page":"1208","DOI":"10.1126\/science.1175862","article-title":"Actin, a Central Player in Cell Shape and Movement","volume":"326","author":"Pollard T. 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