{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T10:18:47Z","timestamp":1787653127654,"version":"build-2736575974"},"reference-count":95,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T00:00:00Z","timestamp":1787616000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T00:00:00Z","timestamp":1787616000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The interplay of multiple noncovalent interactions offers a powerful strategy for the design of functional supramolecular architectures. Here, we developed a unique series of ternary cocrystal salt\u2010like {coformer1;coformer2;salt} systems in the solid state and in solution to approach the problem of collective binding of halide (Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    , Br\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) or pseudohalide (SCN\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) anion pairs. Exploiting HAT(CN)\n                    <jats:sub>6<\/jats:sub>\n                    \u03c0\u2010acid (coformer1) and oligoresorcinol hydrogen\u2010bond donors (coformer2), we identify five new ternary {coformer1;coformer2;[anion]\n                    <jats:italic>\n                      <jats:sub>n<\/jats:sub>\n                    <\/jats:italic>\n                    } (\n                    <jats:italic>n<\/jats:italic>\n                    \u00a0=\u00a01\u20132) supramolecular synthons that integrate anion\u2013\u03c0 interactions, \u03c0\u2013\u03c0 stacking, and hydrogen bonding, reflecting the intrinsic preferences of components. SC XRD and solution\n                    <jats:sup>1<\/jats:sup>\n                    H\/\n                    <jats:sup>13<\/jats:sup>\n                    C NMR studies demonstrate transferability of the synthons among the relevant binary and ternary crystal phases, as well as between the solid state and solution. DFT+D computational analysis confirms the contribution of all three types of supramolecular interactions to the formation and stability of observed motifs, showing a variable hierarchy of these forces modulated by the structural and electronic features of building blocks. Our results demonstrate that while crystal packing influences solid\u2010state arrangements, system's integrity arises from a balance of cooperation and competition among noncovalent interactions. This establishes a new library of complex supramolecular synthons for further consideration in overall supramolecular design.\n                  <\/jats:p>","DOI":"10.1002\/chem.71501","type":"journal-article","created":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T09:24:35Z","timestamp":1787649875000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Engineering Supramolecular {HAT(CN)\n                    <sub>6<\/sub>\n                    ;Oligoresorcinol;Anion} Synthons and Knots via Cooperating Multimodal Noncovalent Interactions"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8179-4647","authenticated-orcid":false,"given":"Dorota","family":"Glosz","sequence":"first","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa Krakow Poland"},{"name":"Doctoral School of Exact and Natural Sciences Jagiellonian University  Lojasiewicza Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-6476-0669","authenticated-orcid":false,"given":"Joachim","family":"Grzybowski","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-6561-7420","authenticated-orcid":false,"given":"Aleksandra","family":"\u017babi\u0144ska","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-0277-2774","authenticated-orcid":false,"given":"Martyna","family":"Dyczkowska","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5220-4430","authenticated-orcid":false,"given":"Tadeusz M.","family":"Muzio\u0142","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Nicolaus Copernicus University in Toru\u0144, Gagarina, Toru\u0144  Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4211-325X","authenticated-orcid":false,"given":"Monika","family":"Srebro\u2010Hooper","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7457-6799","authenticated-orcid":false,"given":"Robert","family":"Podgajny","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,25]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.ccr.2020.213327","article-title":"Emergence of Anion\u2010\u03c0 Interactions: The Land of Opportunity in Supramolecular Chemistry and Beyond","volume":"415","author":"Rather I. A.","year":"2020","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","first-page":"1364","DOI":"10.1021\/acs.accounts.0c00243","article-title":"Exploring Anion\u2212\u03c0 Interactions and Their Applications in Supramolecular Chemistry","volume":"53","author":"Wang D.\u2010X.","year":"2020","journal-title":"Accounts of Chemical Research"},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","DOI":"10.1002\/ejoc.202201281","article-title":"Anion\u2010\u03c0 Interaction for Molecular Recognition of Anions: Focus on Cooperativity with Hydrogen Bonding","volume":"26","author":"Plais R.","year":"2023","journal-title":"European Journal of Organic Chemistry"},{"key":"e_1_2_7_5_1","doi-asserted-by":"crossref","first-page":"531","DOI":"10.1038\/s41586-023-06637-w","article-title":"Anion\u2013\u03c0 Interactions Suppress Phase Impurities in FAPbI3 Solar Cells","volume":"623","author":"Huang Z.","year":"2023","journal-title":"Nature"},{"key":"e_1_2_7_6_1","doi-asserted-by":"crossref","first-page":"4360","DOI":"10.1039\/D5OB00245A","article-title":"Electron\u2010deficient Hemicryptophanes for the Recognition of Anions Through Anion\u2013\u03c0 Interactions","volume":"23","author":"Miton L.","year":"2025","journal-title":"Organic & Biomolecular Chemistry"},{"key":"e_1_2_7_7_1","doi-asserted-by":"crossref","first-page":"4531","DOI":"10.1039\/D4CC06077F","article-title":"A Sulfone\u2010functionalized Molecular Triangle as a Strong Anion Receptor Driven by Anion\u2013\u03c0 Interactions","volume":"61","author":"Ma Y.","year":"2025","journal-title":"Chemical Communications"},{"key":"e_1_2_7_8_1","doi-asserted-by":"crossref","first-page":"971","DOI":"10.1016\/j.chempr.2023.12.024","article-title":"A Multifunctional Pseudo\u2010[6]oxocarbon Molecule Innate to Six Accessible Oxidation States","volume":"10","author":"Pakulski P.","year":"2024","journal-title":"Chem"},{"key":"e_1_2_7_9_1","doi-asserted-by":"crossref","first-page":"13273","DOI":"10.1021\/jacs.0c02881","article-title":"Artificial Chloride\u2010Selective Channel: Shape and Function Mimic of the ClC Channel Selective Pore","volume":"142","author":"Huang W.\u2010L.","year":"2020","journal-title":"Journal of the American Chemical Society"},{"key":"e_1_2_7_10_1","doi-asserted-by":"crossref","DOI":"10.1002\/chem.202304222","article-title":"Mimicking the Shape and Function of the ClC Chloride Channel Selective Pore by Combining a Molecular Hourglass Shape With Anion\u2013\u03c0 Interactions","volume":"30","author":"Huang W.","year":"2024","journal-title":"Chemistry \u2013 A European Journal"},{"key":"e_1_2_7_11_1","doi-asserted-by":"crossref","first-page":"12037","DOI":"10.1002\/anie.201904808","article-title":"Self\u2010Assembled Columnar Triazole Quartets: An Example of Synergistic Hydrogen\u2010Bonding\/Anion\u2013\u03c0 Interactions","volume":"58","author":"Zheng S.","year":"2019","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_12_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202310393","article-title":"Anion\u2010(\u03c0)n\u2010\u03c0 Catalytic Micelles","volume":"62","author":"Tan M.","year":"2023","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_13_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202115961","article-title":"Anion\u2013\u03c0 Catalysis Enabled by the Mechanical Bond**","volume":"61","author":"Maynard J. R. J.","year":"2022","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_14_1","doi-asserted-by":"crossref","first-page":"6183","DOI":"10.1021\/acs.inorgchem.4c05562","article-title":"Anion\u2013\u03c0(\u2013\u03c0) Interactions in Donor\u2013Acceptor Hybrid Materials to Control Photochromism and Room\u2010Temperature Phosphorescence","volume":"64","author":"Di Y.\u2010M.","year":"2025","journal-title":"Inorganic Chemistry"},{"key":"e_1_2_7_15_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202305108","article-title":"Fast and Tunable Phosphorescence From Organic Ionic Crystals","volume":"62","author":"Partanen I.","year":"2023","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_16_1","doi-asserted-by":"crossref","first-page":"7142","DOI":"10.1039\/D6DT00592F","article-title":"Anion(I\u2013)\u2013\u03c0(bisphosphonium)2+ Photoluminescence Enhanced by [Pt(CN)2(Me\u2010phpy)]\u2013","volume":"55","author":"Glosz D.","year":"2026","journal-title":"Dalton Transactions"},{"key":"e_1_2_7_17_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.dyepig.2023.111730","article-title":"Photochromism and Electrochromism in Pyridinium\u2010Annelated Perylene Diimide Salts via Charge\u2010Assisted Anion\u2010\u03c0 Interactions","volume":"220","author":"Lin M.\u2010H.","year":"2023","journal-title":"Dyes and Pigments"},{"key":"e_1_2_7_18_1","doi-asserted-by":"crossref","first-page":"2364","DOI":"10.1039\/C8CC09834D","article-title":"Anion\u2013\u03c0 Interactions in Lithium\u2013Organic Redox Flow Batteries","volume":"55","author":"Li L.","year":"2019","journal-title":"Chemical Communications"},{"key":"e_1_2_7_19_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202503396","article-title":"Coupling Zn2+ Ferrying Effect With Anion\u2013\u03c0 Interaction to Mitigate Space Charge Layer Enables Ultra\u2010High Utilization Rate Zn Anode","volume":"64","author":"Zhang Z.","year":"2025","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_20_1","doi-asserted-by":"crossref","first-page":"2441","DOI":"10.1039\/D2CC06875C","article-title":"Anion\u2013\u03c0 Interaction Inside the Polyanionic Mo132O372 Cage With Hydrophobic Inner Space","volume":"59","author":"Murata C.","year":"2023","journal-title":"Chemical Communications"},{"key":"e_1_2_7_21_1","doi-asserted-by":"crossref","first-page":"2255","DOI":"10.1021\/acs.accounts.8b00223","article-title":"The Emergence of Anion\u2212\u03c0 Catalysis","volume":"51","author":"Zhao Y.","year":"2018","journal-title":"Accounts of Chemical Research"},{"key":"e_1_2_7_22_1","doi-asserted-by":"crossref","first-page":"894","DOI":"10.1021\/ar300251k","article-title":"Anion\u2212\u03c0 Interactions in Supramolecular Architectures","volume":"46","author":"Chifotides H. T.","year":"2013","journal-title":"Accounts of Chemical Research"},{"key":"e_1_2_7_23_1","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1016\/j.ccr.2019.06.016","article-title":"Anion\u2010\u03c0 and Lone Pair\u2010\u03c0 Interactions With s\u2010tetrazine\u2010based Ligands","volume":"397","author":"Savastano M.","year":"2019","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_24_1","doi-asserted-by":"crossref","first-page":"8867","DOI":"10.1021\/acs.chemrev.5b00156","article-title":"Anion\u2212\u03c0 Interactions With Fluoroarenes","volume":"115","author":"Giese M.","year":"2015","journal-title":"Chemical Reviews"},{"key":"e_1_2_7_25_1","doi-asserted-by":"crossref","first-page":"535","DOI":"10.1016\/S0379-6779(01)00342-3","article-title":"HAT(CN)6: A New Building Block for Molecule\u2010Based Magnetic Materials","volume":"122","author":"Szalay P. S.","year":"2001","journal-title":"Synthetic Metals"},{"key":"e_1_2_7_26_1","doi-asserted-by":"crossref","first-page":"503","DOI":"10.1007\/s10876-004-5772-6","article-title":"Experimental and Computational Studies of Charge\u2010Transfer and Reduction Products of 1, 4, 5, 8, 9, 11\u2010Hexaazatriphenylene\u2010Hexacarbonitrile: HAT\u2010(CN)6","volume":"15","author":"Szalay P. S.","year":"2004","journal-title":"Journal of Cluster Science"},{"key":"e_1_2_7_27_1","doi-asserted-by":"crossref","first-page":"7360","DOI":"10.1002\/ange.201001755","article-title":"The \u03c0\u2010Accepting Arene HAT(CN)6 as a Halide Receptor through Charge Transfer: Multisite Anion Interactions and Self\u2010Assembly in Solution and the Solid State","volume":"122","author":"Chifotides H. T.","year":"2010","journal-title":"Angewandte Chemie"},{"key":"e_1_2_7_28_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.ccr.2026.217616","article-title":"Anion\u00b7\u00b7\u00b7\u03c0 Interactions and Hydrogen Bonds in Cyanidometallate\u2010Based co\u2010Crystal Systems: Novel Synthons, Functional Properties, and Stories Behind Them","volume":"556","author":"Glosz D.","year":"2026","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_29_1","doi-asserted-by":"crossref","DOI":"10.1002\/chem.70917","article-title":"Hierarchy and Synergy of Anion\u2010\u03c0, Hydrogen Bonding and \u03c0\u2010\u03c0 Interactions in Multicomponent Ionic Hybrid Architectures","volume":"32","author":"Glosz D.","year":"2026","journal-title":"Chemistry \u2013 A European Journal"},{"key":"e_1_2_7_30_1","doi-asserted-by":"crossref","first-page":"2620","DOI":"10.1021\/ja309960m","article-title":"Different Nature of the Interactions Between Anions and HAT(CN)6: From Reversible Anion\u2212\u03c0 Complexes to Irreversible Electron\u2010Transfer Processes (HAT(CN)6 = 1,4,5,8,9,12\u2010Hexaazatriphenylene)","volume":"135","author":"Aragay G.","year":"2013","journal-title":"Journal of the American Chemical Society"},{"key":"e_1_2_7_31_1","doi-asserted-by":"crossref","first-page":"13679","DOI":"10.1021\/ja303173n","article-title":"Boundaries of Anion\/Naphthalenediimide Interactions: From Anion\u2212\u03c0 Interactions to Anion\u2010Induced Charge\u2010Transfer and Electron\u2010Transfer Phenomena","volume":"134","author":"Guha S.","year":"2012","journal-title":"Journal of the American Chemical Society"},{"key":"e_1_2_7_32_1","doi-asserted-by":"crossref","first-page":"11941","DOI":"10.1039\/C8CC06522E","article-title":"An Electron\u2010deficient Nanosized Polycyclic Aromatic Hydrocarbon With Enhanced Anion\u2013\u03c0 Interactions","volume":"54","author":"Li L.","year":"2018","journal-title":"Chemical Communications"},{"key":"e_1_2_7_33_1","doi-asserted-by":"crossref","first-page":"170","DOI":"10.1039\/D0DT03535A","article-title":"Binding of Anionic Pt(ii) Complexes in a Dedicated Organic Matrix: Towards New Binary Crystalline Composites","volume":"50","author":"Kuzniak\u2010Glanowska E.","year":"2021","journal-title":"Dalton Transactions"},{"key":"e_1_2_7_34_1","doi-asserted-by":"crossref","first-page":"16302","DOI":"10.1002\/chem.201802933","article-title":"Molecular Deformation, Charge Flow, and Spongelike Behavior in Anion\u2013\u03c0 {[M(CN)4]2\u2212;[HAT(CN)6]}\u221e (M=Ni, Pd, Pt) Supramolecular Stacks","volume":"24","author":"Kuzniak E.","year":"2018","journal-title":"Chemistry \u2013 A European Journal"},{"key":"e_1_2_7_35_1","doi-asserted-by":"crossref","first-page":"3482","DOI":"10.1039\/C7DT00293A","article-title":"Anion\u2013\u03c0 Recognition Between [M(CN)6]3\u2212 Complexes and HAT(CN)6: Structural Matching and Electronic Charge Density Modification","volume":"46","author":"Kobylarczyk J.","year":"2017","journal-title":"Dalton Transactions"},{"key":"e_1_2_7_36_1","doi-asserted-by":"crossref","first-page":"1215","DOI":"10.1021\/acs.cgd.8b01653","article-title":"Anion\u2010\u03c0 Architectures of HAT(CN)6 and 5d Polycyanidometalates: [W(CN)8]3\u2013, [Re(CN)7]3\u2013, and [Pt(CN)6]2\u2013","volume":"19","author":"Kobylarczyk J.","year":"2019","journal-title":"Crystal Growth & Design"},{"key":"e_1_2_7_37_1","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1021\/acs.cgd.1c00793","article-title":"Synthesis of Hexaazatriphenylene Charge\u2010Transfer Complexes and Their Application in Cathode Active Materials for Lithium\u2010Ion Batteries","volume":"22","author":"Nakao K.","year":"2022","journal-title":"Crystal Growth & Design"},{"key":"e_1_2_7_38_1","doi-asserted-by":"crossref","first-page":"1851","DOI":"10.1039\/D0QI00101E","article-title":"A Concerted Evolution of Supramolecular Interactions in a {cation; metal complex; \u03c0\u2010acid; solvent} anion\u2010\u03c0 system","volume":"7","author":"Kuzniak E.","year":"2020","journal-title":"Inorganic Chemistry Frontiers"},{"key":"e_1_2_7_39_1","doi-asserted-by":"crossref","first-page":"6301","DOI":"10.1039\/D5SC08607H","article-title":"Peptide Cages: Bioinspired Supramolecular Architectures for Next\u2010Generation Applications","volume":"17","author":"Adorinni S.","year":"2026","journal-title":"Chemical Science"},{"key":"e_1_2_7_40_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202507102","article-title":"From Binary to Higher\u2010Order Organic Cocrystals: Design Principles and Performance Optimization","volume":"64","author":"Jiang J.","year":"2025","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_41_1","doi-asserted-by":"crossref","first-page":"11514","DOI":"10.1021\/acs.chemrev.1c00987","article-title":"Crystal Engineering of Pharmaceutical Cocrystals in the Discovery and Development of Improved Drugs","volume":"122","author":"Bolla G.","year":"2022","journal-title":"Chemical Reviews"},{"key":"e_1_2_7_42_1","doi-asserted-by":"crossref","first-page":"16770","DOI":"10.1039\/D5CC01707F","article-title":"The Whole is Greater Than the Sum of Its Parts: Binary and Ternary 5\u2010fluorouracil co\u2010crystals With Enhanced Selectivity towards Metastatic Cancer Cells","volume":"61","author":"Grabowski S.","year":"2025","journal-title":"Chemical Communications"},{"key":"e_1_2_7_43_1","doi-asserted-by":"crossref","first-page":"12027","DOI":"10.1002\/anie.201904339","article-title":"From a Binary to a Quaternary Cocrystal: An Unusual Supramolecular Synthon","volume":"58","author":"Paul M.","year":"2019","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_44_1","doi-asserted-by":"crossref","DOI":"10.1002\/chem.202300954","article-title":"Structural Conversion of Supramolecular Assembly in Solution by Thermally Induced Intramolecular Electron Transfer of [Co2Fe2] Complex","volume":"29","author":"Mihara N.","year":"2023","journal-title":"Chemistry \u2013 A European Journal"},{"key":"e_1_2_7_45_1","doi-asserted-by":"crossref","first-page":"3510","DOI":"10.1038\/s41467-022-31274-8","article-title":"A Spin\u2010crossover Framework Endowed With Pore\u2010Adjustable Behavior by Slow Structural Dynamics","volume":"13","author":"Xue J.\u2010P.","year":"2022","journal-title":"Nature Communications"},{"key":"e_1_2_7_46_1","doi-asserted-by":"crossref","DOI":"10.1002\/chem.70378","article-title":"Tautomerism\u2010Coupled Self\u2010Assembly and Transformations of Iminopyrrole Metallacages","volume":"31","author":"Sukiennik J.","year":"2025","journal-title":"Chemistry \u2010 A European Journal"},{"key":"e_1_2_7_47_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202517109","article-title":"Proton Conduction, Dielectric Relaxation, Photoluminescence, and Photochromism Governed by Humidity and Alcohol Vapors in a Uranyl\u2013Cobalt Framework With Labile Coordination Sites","volume":"64","author":"Zakrzewski J. J.","year":"2025","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_48_1","doi-asserted-by":"crossref","first-page":"1118","DOI":"10.1039\/D5QI01915J","article-title":"Proton Conductivity and Magnetization Photoswitching in CN\u2010bridged CuII\n                  3MIV\n                  2 Molecules (M = Mo, W) based on Carboxy\u2010Functionalized Macrocyclic Ligand","volume":"13","author":"Reczy\u0144ski M.","year":"2026","journal-title":"Inorganic Chemistry Frontiers"},{"key":"e_1_2_7_49_1","doi-asserted-by":"crossref","first-page":"9651","DOI":"10.1039\/D3SC03255H","article-title":"Guest\u2010induced Pore Breathing Controls the Spin state in a Cyanido\u2010Bridged Framework","volume":"14","author":"Magott M.","year":"2023","journal-title":"Chemical Science"},{"key":"e_1_2_7_50_1","doi-asserted-by":"crossref","first-page":"6845","DOI":"10.1039\/c3ce40761f","article-title":"Synthesis, Topology and Energy Analysis of Crystalline Resorcinol\u2010Based Oligophenylene Molecules With Various Symmetries","volume":"15","author":"Chaumont C.","year":"2013","journal-title":"CrystEngComm"},{"key":"e_1_2_7_51_1","doi-asserted-by":"crossref","first-page":"962","DOI":"10.1021\/ct800503d","article-title":"A Combined Charge and Energy Decomposition Scheme for Bond Analysis","volume":"5","author":"Mitoraj M. P.","year":"2009","journal-title":"Journal of Chemical Theory and Computation"},{"key":"e_1_2_7_52_1","doi-asserted-by":"crossref","first-page":"11608","DOI":"10.1039\/C7DT02821K","article-title":"Lewis Basicity of Relevant Monoanions in a Non\u2010Protogenic Organic Solvent Using a Zinc(ii) Schiff\u2010Base Complex as a Reference Lewis Acid","volume":"46","author":"Pietro Oliveri I.","year":"2017","journal-title":"Dalton Transactions"},{"key":"e_1_2_7_53_1","doi-asserted-by":"crossref","first-page":"3131","DOI":"10.1039\/C4CP04687K","article-title":"Photoelectron Spectroscopy and Theoretical Studies of Anion\u2013\u03c0 Interactions: Binding Strength and Anion Specificity","volume":"17","author":"Zhang J.","year":"2015","journal-title":"Physical Chemistry Chemical Physics"},{"key":"e_1_2_7_54_1","doi-asserted-by":"crossref","first-page":"14077","DOI":"10.1021\/jp709634t","article-title":"Ion Pairing as a Possible Clue for Discriminating Between Sodium and Potassium in Biological and Other Complex Environments","volume":"111","author":"Jagoda\u2010Cwiklik B.","year":"2007","journal-title":"Journal of Physical Chemistry B"},{"key":"e_1_2_7_55_1","doi-asserted-by":"crossref","first-page":"5095","DOI":"10.1039\/D2OB00880G","article-title":"Three Modes of Interactions Between Anions and Phenolic Macrocycles: A Comparative Study","volume":"20","author":"Abdurakhmanova E. R.","year":"2022","journal-title":"Organic & Biomolecular Chemistry"},{"key":"e_1_2_7_56_1","doi-asserted-by":"crossref","first-page":"8401","DOI":"10.1021\/acs.jpcc.0c00672","article-title":"Influence of Glycoluril Molecular Clip Isomerization on the Mechanisms of Resorcinol Molecule Complexation","volume":"124","author":"Gosecki M.","year":"2020","journal-title":"Journal of Physical Chemistry C"},{"key":"e_1_2_7_57_1","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1002\/chem.200801643","article-title":"Anion\u2013\u03c0 Slides for Transmembrane Transport","volume":"15","author":"Mareda J.","year":"2009","journal-title":"Chemistry \u2013 A European Journal"},{"key":"e_1_2_7_58_1","doi-asserted-by":"crossref","first-page":"8324","DOI":"10.1021\/ja4021793","article-title":"Quantification of Nitrate\u2212\u03c0 Interactions and Selective Transport of Nitrate Using Calix[4]Pyrroles With Two Aromatic Walls","volume":"135","author":"Adriaenssens L.","year":"2013","journal-title":"Journal of the American Chemical Society"},{"key":"e_1_2_7_59_1","doi-asserted-by":"crossref","first-page":"11139","DOI":"10.1039\/C6CC04562F","article-title":"Probing and Evaluating Anion\u2013\u03c0 Interaction in Meso\u2010Dinitrophenyl Functionalized Calix[4]Pyrrole Isomers","volume":"52","author":"Kim A.","year":"2016","journal-title":"Chemical Communications"},{"key":"e_1_2_7_60_1","doi-asserted-by":"crossref","first-page":"14128","DOI":"10.1021\/ja506278z","article-title":"Hopping\u2010Mediated Anion Transport Through a Mannitol\u2010Based Rosette Ion Channel","volume":"136","author":"Saha T.","year":"2014","journal-title":"Journal of the American Chemical Society"},{"key":"e_1_2_7_61_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.ccr.2023.215451","article-title":"Photoswitchable Diarylethenes: From Molecular Structures to Biological Applications","volume":"497","author":"Li Z.","year":"2023","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_62_1","doi-asserted-by":"crossref","DOI":"10.1002\/cbic.202400326","article-title":"Recent Progress of Photoswitchable Fluorescent Diarylethenes for Bioimaging","volume":"25","author":"Qin K.","year":"2024","journal-title":"Chembiochem"},{"key":"e_1_2_7_63_1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1038\/s41570-021-00334-w","article-title":"Advances and Opportunities in the Exciting World of Azobenzenes","volume":"6","author":"Jerca F. A.","year":"2021","journal-title":"Nature Reviews Chemistry"},{"key":"e_1_2_7_64_1","doi-asserted-by":"crossref","first-page":"446","DOI":"10.1038\/s41557-023-01389-6","article-title":"Azobenzene as a Photoswitchable Mechanophore","volume":"16","author":"Li Y.","year":"2024","journal-title":"Nature Chemistry"},{"key":"e_1_2_7_65_1","doi-asserted-by":"crossref","first-page":"19609","DOI":"10.1021\/jacs.4c03135","article-title":"Visible\u2010Light\u2010Activated Heteroaryl Azoswitches: Toward a More Colorful Future","volume":"146","author":"Dang T.","year":"2024","journal-title":"Journal of the American Chemical Society"},{"key":"e_1_2_7_66_1","doi-asserted-by":"crossref","first-page":"2244","DOI":"10.1021\/acscatal.0c05232","article-title":"Dithienylethene\u2010Based Photoswitchable Catalysts: State of the Art and Future Perspectives","volume":"11","author":"Majee D.","year":"2021","journal-title":"ACS Catalysis"},{"key":"e_1_2_7_67_1","doi-asserted-by":"crossref","first-page":"16295","DOI":"10.1021\/acs.inorgchem.2c01999","article-title":"Low\u2010Coordinate Erbium(III) Single\u2010Molecule Magnets With Photochromic Behavior","volume":"61","author":"Rogacz K.","year":"2022","journal-title":"Inorganic Chemistry"},{"key":"e_1_2_7_68_1","doi-asserted-by":"crossref","first-page":"2068","DOI":"10.1016\/j.ccr.2011.02.004","article-title":"Thermo\u2010, Piezo\u2010, Photo\u2010 and Chemo\u2010Switchable Spin Crossover Iron(II)\u2010metallocyanate Based Coordination Polymers","volume":"255","author":"Mu\u00f1oz M. C.","year":"2011","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_69_1","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1039\/C5CS00321K","article-title":"Switchable Fe\/Co Prussian Blue Networks and Molecular Analogues","volume":"45","author":"Aguil\u00e0 D.","year":"2016","journal-title":"Chemical Society Reviews"},{"key":"e_1_2_7_70_1","doi-asserted-by":"crossref","first-page":"24","DOI":"10.1016\/j.ccr.2018.02.001","article-title":"Spin Crossover in Homoleptic Fe(II) Imidazolylimine Complexes","volume":"362","author":"Scott H. S.","year":"2018","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_71_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.ccr.2025.217363","article-title":"Cyanide Cubic Cages: Soluble Molecular Counterparts of Prussian Blue Analogues","volume":"549","author":"Glatz J.","year":"2026","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_72_1","doi-asserted-by":"crossref","first-page":"11187","DOI":"10.1002\/chem.202000146","article-title":"Guest\u2010Dependent Pressure\u2010Induced Spin Crossover in FeII\n                  4[MIV(CN)8]2 (M = Mo, W) Cluster\u2010Based Material Showing Persistent Solvent\u2010Driven Structural Transformations","volume":"26","author":"Jankowski R.","year":"2020","journal-title":"Chemistry \u2013 A European Journal"},{"key":"e_1_2_7_73_1","doi-asserted-by":"crossref","first-page":"15741","DOI":"10.1002\/anie.202007327","article-title":"Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two\u2010Step Iron(II) Spin Crossover Switchable by Temperature, Light, and Pressure","volume":"59","author":"Chorazy S.","year":"2020","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_74_1","doi-asserted-by":"crossref","first-page":"6745","DOI":"10.1039\/D4TC05094K","article-title":"Chemically Driven Magnetic Responsivity to Multiple Physical Stimuli in a Spin\u2010Crossover Layered Iron(ii)\u2013Rhenium(v) Framework","volume":"13","author":"Charytanowicz T.","year":"2025","journal-title":"Journal of Materials Chemistry C"},{"key":"e_1_2_7_75_1","first-page":"4310","article-title":"Facile Synthesis of Naphthalene Diimide (NDI) Derivatives: Aggregation\u2010induced Emission, Photophysical and Transport Properties","volume":"31","author":"Kumari N.","year":"2020","journal-title":"Journal of Materials Science: Materials in Electronics"},{"key":"e_1_2_7_76_1","doi-asserted-by":"crossref","first-page":"25005","DOI":"10.1002\/anie.202110139","article-title":"Molecular Encapsulation of Naphthalene Diimide (NDI) Based \u03c0\u2010Conjugated Polymers: A Tool for Understanding Photoluminescence","volume":"60","author":"Royakkers J.","year":"2021","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_7_77_1","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202310071","article-title":"Mechanical, Morphological, and Charge Transport Properties of NDI Polymers With Variable Built\u2010in \u03a0\u2010Conjugation Lengths Probed by Simulation and Experiment","volume":"34","author":"Zhao D.","year":"2024","journal-title":"Advanced Functional Materials"},{"key":"e_1_2_7_78_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.scitotenv.2021.146483","article-title":"Review on Application of Perylene Diimide (PDI)\u2010Based Materials in Environment: Pollutant Detection and Degradation","volume":"780","author":"Zhou W.","year":"2021","journal-title":"Science of The Total Environment"},{"key":"e_1_2_7_79_1","doi-asserted-by":"crossref","first-page":"309","DOI":"10.1021\/accountsmr.1c00191","article-title":"Perylene Diimide\u2010Based Oligomers and Polymers for Organic Optoelectronics","volume":"3","author":"Cheng P.","year":"2022","journal-title":"Accounts of Materials Research"},{"key":"e_1_2_7_80_1","doi-asserted-by":"crossref","first-page":"3807","DOI":"10.1039\/D3TA06862E","article-title":"Recent Progress in Perylene Diimide Supermolecule\u2010Based Photocatalysts","volume":"12","author":"Yang B.","year":"2024","journal-title":"Journal of Materials Chemistry A"},{"key":"e_1_2_7_81_1","doi-asserted-by":"crossref","first-page":"1829","DOI":"10.1021\/acscatal.4c07066","article-title":"Molecular Design of Perylene Diimide Derivatives for Photocatalysis","volume":"15","author":"Li Z.","year":"2025","journal-title":"ACS Catalysis"},{"key":"e_1_2_7_82_1","unstructured":"Deposition numbers 2533586 (for H\/PG\/PSCN) 2533579 (for H\/DiR\/PBr) 2533578 (for H\/DiR\/NBr) 2533583 (for H\/DiRB\/PBr) 2533584 (for H\/DiRB\/PSCN) 2533581 (for H\/DiR) 2533585 (for H\/DiRB) 2533565 (for DiR\/PBr) 2533562 (for DiR\/NBr) 2533566 (for DiRB\/PBr) and 2533569 (for DiRB\/PSCN) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."},{"key":"e_1_2_7_83_1","doi-asserted-by":"crossref","first-page":"378","DOI":"10.1055\/s-1994-25480","article-title":"Improved Synthesis of 1,4,5,8,9,12\u2010Hexaazatriphenylenehexacarboxylic Acid","volume":"4","author":"Rademacher J. T.","year":"1994","journal-title":"Synthesis"},{"key":"e_1_2_7_84_1","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A Short History of SHELX","volume":"64","author":"Sheldrick G. M.","year":"2008","journal-title":"Acta Crystallographica Section A Foundations of Crystallography"},{"key":"e_1_2_7_85_1","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","article-title":"OLEX2: A Complete Structure Solution, Refinement and Analysis Program","volume":"42","author":"Dolomanov O. V.","year":"2009","journal-title":"Journal of Applied Crystallography"},{"key":"e_1_2_7_86_1","first-page":"3","article-title":"Crystal Structure Refinement With SHELXL","volume":"71","author":"Sheldrick G. M.","year":"2015","journal-title":"Acta Crystallographica Section C: Structural Chemistry"},{"key":"e_1_2_7_87_1","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","article-title":"Mercury 4.0: From Visualization to Analysis, Design and Prediction","volume":"53","author":"Macrae C. F.","year":"2020","journal-title":"Journal of Applied Crystallography"},{"key":"e_1_2_7_88_1","unstructured":"ADF 2023.101 SCM Theoretical Chemistry Vrije Universiteit Amsterdam The Netherlands http:\/\/www.scm.com. E. J.Baerends T.Ziegler A. J.Atkins et\u00a0al. 2023."},{"key":"e_1_2_7_89_1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/j.cplett.2004.06.011","article-title":"A New Hybrid Exchange\u2013Correlation Functional Using the Coulomb\u2010Attenuating Method (CAM\u2010B3LYP)","volume":"393","author":"Yanai T.","year":"2004","journal-title":"Chemical Physics Letters"},{"key":"e_1_2_7_90_1","doi-asserted-by":"crossref","first-page":"1142","DOI":"10.1002\/jcc.10255","article-title":"Optimized Slater\u2010Type Basis Sets for the Elements 1\u2013118","volume":"24","author":"Van Lenthe E.","year":"2003","journal-title":"Journal of Computational Chemistry"},{"key":"e_1_2_7_91_1","doi-asserted-by":"crossref","DOI":"10.1063\/1.5090222","article-title":"A Generally Applicable Atomic\u2010Charge Dependent London Dispersion Correction","volume":"150","author":"Caldeweyher E.","year":"2019","journal-title":"Journal of Chemical Physics"},{"key":"e_1_2_7_92_1","doi-asserted-by":"crossref","DOI":"10.1063\/1.4993215","article-title":"Extension of the D3 Dispersion Coefficient Model","volume":"147","author":"Caldeweyher E.","year":"2017","journal-title":"Journal of Chemical Physics"},{"key":"e_1_2_7_93_1","doi-asserted-by":"crossref","first-page":"32184","DOI":"10.1039\/C7CP04913G","article-title":"A Look at the Density Functional Theory Zoo With the Advanced GMTKN55 Database for General Main Group Thermochemistry, Kinetics and Noncovalent Interactions","volume":"19","author":"Goerigk L.","year":"2017","journal-title":"Physical Chemistry Chemical Physics"},{"key":"e_1_2_7_94_1","doi-asserted-by":"crossref","first-page":"5129","DOI":"10.1021\/acs.jpca.9b03157","article-title":"Minimally Empirical Double\u2010Hybrid Functionals Trained Against the GMTKN55 Database: RevDSD\u2010PBEP86\u2010D4, revDOD\u2010PBE\u2010D4, and DOD\u2010SCAN\u2010D4","volume":"123","author":"Santra G.","year":"2019","journal-title":"Journal of Physical Chemistry A"},{"key":"e_1_2_7_95_1","doi-asserted-by":"crossref","first-page":"9783","DOI":"10.1063\/1.467943","article-title":"Relativistic Total Energy Using Regular Approximations","volume":"101","author":"Van Lenthe E.","year":"1994","journal-title":"Journal of Chemical Physics"},{"key":"e_1_2_7_96_1","unstructured":"\u201cSCM Documentation \u201d can be found under https:\/\/www.scm.com\/doc\/ADF\/Input\/BSSE.html(accessed June 3 2025) 2025."}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71501","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71501","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71501","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T09:24:46Z","timestamp":1787649886000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71501"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,25]]},"references-count":95,"alternative-id":["10.1002\/chem.71501"],"URL":"https:\/\/doi.org\/10.1002\/chem.71501","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,25]]},"assertion":[{"value":"2026-05-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71501"}}