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This method is efficient, general and achieved in mild conditions starting from xanthates derivatives and using triethylborane as initiator and 4\u2010tert\u2010butylcatechol as hydrogen atom source. This hydroalkylation reaction is completely regioselective with moderate to complete stereoselectivity.<\/jats:p>","DOI":"10.1002\/chem.71515","type":"journal-article","created":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T15:23:10Z","timestamp":1785770590000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Stereoselective Synthesis of \u03b2\u2010\n                    <i>C<\/i>\n                    \u2010glycosides From Exoglycals Through Radical C\u2500C Bond Formation"],"prefix":"10.1002","author":[{"given":"No\u00e9mie","family":"Murard","sequence":"first","affiliation":[{"name":"Institut De Chimie et Biochimie Mol\u00e9culaires Et Supramol\u00e9culaires Laboratoire De Chimie Organique 2\u2014Glycochimie UMR\u2010CNRS 5246\u2010Universit\u00e9 Claude Bernard Lyon 1  France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0548-0651","authenticated-orcid":false,"given":"Guillaume","family":"Pilet","sequence":"additional","affiliation":[{"name":"Laboratoire Des Multimat\u00e9riaux et Interfaces UMR\u2010CNRS 5615\u2010Universit\u00e9 Claude Bernard Lyon 1  France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9657-3836","authenticated-orcid":false,"given":"David","family":"Gueyrard","sequence":"additional","affiliation":[{"name":"Institut De Chimie et Biochimie Mol\u00e9culaires Et Supramol\u00e9culaires Laboratoire De Chimie Organique 2\u2014Glycochimie UMR\u2010CNRS 5246\u2010Universit\u00e9 Claude Bernard Lyon 1  France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,3]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1136\/oem.7.3.122"},{"key":"e_1_2_7_3_1","volume-title":"Transition Metal Reagents and Catalysts: Innovations in Organic Synthesis","author":"Tsuji J.","year":"2010"},{"key":"e_1_2_7_4_1","volume-title":"Metal\u2010catalyzed Cross\u2010coupling Reactions","author":"Diederich F.","year":"2001"},{"key":"e_1_2_7_5_1","doi-asserted-by":"crossref","first-page":"2725","DOI":"10.1021\/cr068352x","article-title":"Photocatalysis for the Formation of the C\u2212C Bond","volume":"107","author":"Fagnoni M.","year":"2007","journal-title":"Chemical Reviews"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2017.01.035"},{"key":"e_1_2_7_7_1","first-page":"rn00698","volume-title":"Encyclopedia of Reagents for Organic Synthesis","author":"Charrier N.","year":"2007"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1055\/a\u20101965\u20103028"},{"key":"e_1_2_7_9_1","doi-asserted-by":"crossref","first-page":"572","DOI":"10.1055\/s-2004-815434","article-title":"Triethylborane (Et3 B)","volume":"2004","author":"O'Mahony G.","year":"2004","journal-title":"Synlett"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr010001p"},{"key":"e_1_2_7_11_1","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1021\/cr030640v","article-title":"Synthesis and Uses of Exo \u2010Glycals","volume":"104","author":"Taillefumier C.","year":"2004","journal-title":"Chemical Reviews"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104020(97)10007\u20102"},{"key":"e_1_2_7_13_1","doi-asserted-by":"crossref","first-page":"1253","DOI":"10.1039\/CC9960001253","article-title":"Glycomimetics via a New Glycoexoenitols\u2013Malonyl Radical C\u2013C Bond Formation","volume":"32","author":"Cipolla L.","year":"1996","journal-title":"Chemical Communications"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104020(97)01021\u20101"},{"key":"e_1_2_7_15_1","doi-asserted-by":"crossref","first-page":"19648","DOI":"10.1021\/jacs.1c11059","article-title":"Photochemical C\u2013F Activation Enables Defluorinative Alkylation of Trifluoroacetates and \u2010Acetamides","volume":"143","author":"Campbell M. 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