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To address these issues, this work regulates the ratio of iron\u2010based metal alcoholate ligands by the hydrothermal method and constructs nanoflower\u2010like nanostructures with crystalline and amorphous coupling through etching, thereby improving the catalytic activity. Among them, Fe\u2010gly\u20101.5 demonstrates exceptional catalytic performance under high current density, evidenced by a 243\u00a0mV overpotential (100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) and 200\u00a0h stability (250\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ). Moreover, the two\u2010electrode alkaline water electrolyzer assembled with Fe\u2010gly\u20101.5 and Pt\/C catalysts shows sustainable stability in the overall water splitting process. Electrochemical studies using probe molecules such as TMAOH and methanol demonstrate that the mixed\u2011ligand system exhibits unique advantages in catalytic reactions. Further investigations through in situ Raman and Fourier transform infrared (FTIR) spectroscopy, combined with differential electrochemical mass spectrometry (DEMS), reveal that the active phase of Fe\u2010gly\u20101.5 is \u03b4\/\u03b2\u2010FeOOH formed via reconstruction during the OER process, and confirm that its reaction pathway follows the lattice oxygen\u2010mediated mechanism (LOM).\n                  <\/jats:p>","DOI":"10.1002\/chem.71523","type":"journal-article","created":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T06:35:01Z","timestamp":1786170901000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Iron Alcoholate\u2010Derived FeOOH Nanoflowers Enabling Lattice Oxygen\u2010Mediated Oxygen Evolution"],"prefix":"10.1002","author":[{"given":"Mengjia","family":"Wang","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Materials Protection and Advanced Materials Electric Power 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