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Herein, we report a dual\u2010layer protective structure (Si@MnSiO\n                    <jats:sub>3<\/jats:sub>\n                    @C) constructed through an in\u2010situ conversion reaction followed by chemical vapor deposition carbon coating. The inner MnSiO\n                    <jats:sub>3<\/jats:sub>\n                    layer is derived from the native SiO\n                    <jats:sub>2<\/jats:sub>\n                    layer on Si, forming robust Si\u2500O\u2500Mn covalent bonds that ensure strong interfacial adhesion. The outer carbon layer provides a conductive network and additional structural confinement. This architecture effectively buffers volume expansion, enhances electron transport, and facilitates Li\n                    <jats:sup>+<\/jats:sup>\n                    diffusion kinetics. As a result, the Si@MnSiO\n                    <jats:sub>3<\/jats:sub>\n                    @C composite delivers a high initial Coulombic efficiency of 80.1%, retains 86.1% of its capacity after 100 cycles at 0.5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and maintains a specific capacity of 1334\u00a0mA h g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 600 cycles at 1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , demonstrating excellent cycling stability and rate performance. This work presents a promising strategy for designing high\u2010performance Si\u2010based anodes through interfacial engineering.\n                  <\/jats:p>","DOI":"10.1002\/chem.71532","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T04:27:05Z","timestamp":1785817625000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dual\u2010Layer Protected Silicon Anode With In Situ Converted MnSiO\n                    <sub>3<\/sub>\n                    Interlayer and Carbon Shell for Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"32","author":[{"given":"Pengliang","family":"Gu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering Nanjing University  Nanjing 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Chemical Engineering Nanjing University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering Nanjing University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhan","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering Nanjing University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5293-2323","authenticated-orcid":false,"given":"Hongbin","family":"Du","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering Nanjing University  Nanjing 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