{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T13:31:47Z","timestamp":1786627907664,"version":"build-2736575974"},"reference-count":49,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T00:00:00Z","timestamp":1786579200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T00:00:00Z","timestamp":1786579200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Estrogenic hormones are potent endocrine\u2010disrupting contaminants that are inefficiently removed by conventional wastewater treatment processes. Herein, we evaluate a family of isoreticular amino\u2010acid\u2013derived metal\u2013organic frameworks (MOFs), including multivariate variants, for the simultaneous capture of estrone (E1), 17\u03b2\u2010estradiol (E2), estriol (E3), and 17\u03b1\u2010ethinylestradiol (EE2) from water. Using a solid\u2010phase extraction configuration, a leucine\u2010based oxamidato MOF emerges as a highly efficient sorbent, achieving &gt;90%\u201395% removal of all four hormones within 30 s in a single loading step, representing one of the fastest simultaneous estrogen capture systems reported to date under SPE conditions. This material exhibits exceptional regenerability, enabling near\u2010quantitative desorption under mild conditions with minimal solvent consumption (1\u00a0mL methanol), and stable performance over at least ten reuse cycles. Notably, comparable capture efficiencies are maintained in real river\u2010water samples, demonstrating robustness toward complex aqueous matrices. The crystal structure of a host\u2013guest aggregate confirms estrogen encapsulation within the flexible framework, providing direct structural insight into the origin of the high capture efficiency. These results identify amino\u2010acid\u2013based MOFs as a highly competitive platform for rapid, regenerable, and selective estrogen capture, combining excellent performance with valuable structural insight into host\u2013guest interactions.<\/jats:p>","DOI":"10.1002\/chem.71554","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T12:44:36Z","timestamp":1786625076000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Rapid and Reusable Amino Acid\u2013Derived MOFs for the Removal of Estrogenic Hormones From Real Water Matrices"],"prefix":"10.1002","author":[{"given":"Lidia","family":"Garc\u00eda","sequence":"first","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universidad de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alejandro","family":"Cort\u00e9s\u2010Villena","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry University of Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"H\u00e9ctor Mart\u00ednez","family":"P\u00e9rez\u2010Cejuela","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry University of Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8745-3795","authenticated-orcid":false,"given":"Jos\u00e9 Manuel","family":"Herrero\u2010Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry University of Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jes\u00fas","family":"Ferrando\u2010Soria","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universidad de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thais","family":"Grancha","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universidad de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8502-8074","authenticated-orcid":false,"given":"Donatella","family":"Armentano","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica e Tecnologie Chimiche (CTC) Universit\u00e0 della Calabria  Cosenza Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1394-2553","authenticated-orcid":false,"given":"Emilio","family":"Pardo","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universidad de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,13]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1016\/j.yrtph.2014.02.002","article-title":"Critical Comments on the WHO\u2010UNEP State of the Science of Endocrine Disrupting Chemicals\u20132012","volume":"69","author":"Lamb J. 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