{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T16:22:53Z","timestamp":1786465373462,"version":"build-2736575974"},"reference-count":56,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic biomass\u2010based ethanol coupled with water electrolysis for hydrogen production can significantly reduce hydrogen production energy consumption while generating high\u2010valued acetate. However, nickel\u2010based non\u2010precious metal electrocatalysts exhibit low selectivity and stability due to imbalanced adsorption of ethanol reactants and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    . Herein, Cu\u2010doped Ni(OH)\n                    <jats:sub>2<\/jats:sub>\n                    nanosheets were prepared for the selective electrooxidation of ethanol to acetate, achieving nearly 100% Faradaic efficiency (FE) and 108\u00a0h stability. In situ electrochemical testing and theoretical calculations indicated that Cu doping promoted the cooperative of OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    at Cu sites, thereby effectively switching the rate\u2010determining step from *CH\n                    <jats:sub>3<\/jats:sub>\n                    CHO dehydrogenation to *CH\n                    <jats:sub>3<\/jats:sub>\n                    CO\u2500OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    coupling. This synergistically adsorption mechanism reduces the thermodynamic barrier to 1.56\u00a0eV. Additionally, the constructed dual\u2010electrode system delivered a current density of 50\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at a cell voltage of 1.54\u00a0V, along with over 55\u00a0h stability and high FEs. This work demonstrates the importance of cooperative adsorption behavior of ethanol and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    in the ethanol oxidation process, which is beneficial to enhancing the production efficiency of green hydrogen and acetate through electrochemical methods.\n                  <\/jats:p>","DOI":"10.1002\/chem.71570","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T14:58:17Z","timestamp":1786460297000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrocatalytic Ethanol\u2010to\u2010Acetate Conversion With Nearly 100% Faradaic Efficiency Enabled by Cu\u2010Doping Strategy for Enhancing Selective and Cooperative Adsorption"],"prefix":"10.1002","author":[{"given":"Zihui","family":"Zhu","sequence":"first","affiliation":[{"name":"College of Materials and Chemistry &amp; Chemical Engineering Chengdu University of Technology  Chengdu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjing","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Materials and Chemistry &amp; Chemical Engineering Chengdu University of Technology  Chengdu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maolin","family":"Han","sequence":"additional","affiliation":[{"name":"College of Materials and Chemistry &amp; Chemical Engineering Chengdu University of Technology  Chengdu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yichen","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Materials and Chemistry &amp; Chemical Engineering Chengdu University of Technology  Chengdu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0536-2313","authenticated-orcid":false,"given":"Qiang","family":"Peng","sequence":"additional","affiliation":[{"name":"College of Materials and Chemistry &amp; Chemical Engineering Chengdu University of Technology  Chengdu P. R. China"},{"name":"School of Chemical Engineering and State Key Laboratory of Advanced Polymer Materials Sichuan University  Chengdu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,11]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00332"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202213328"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418504"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301572"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202304065"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505059"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202407473"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202417684"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03022"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305158"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010023\u20106023\u20101"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010022\u201000828\u2010w"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010025\u201001892\u20106"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c01327"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c01679"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202409849"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c05014"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c06639"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20102067(21)63995\u20105"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.07.022"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501773"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420752"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404676"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503745"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411517"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417092"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c07089"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122388"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.4c02596"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA03942K"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202400827"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303557"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058495\u2010x"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506044"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201900528"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00164"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01816K"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.06.011"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c18345"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504993"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2318853121"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010021\u20103930\u2010x"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300094"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202200957"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwae134"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416763"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311766"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c05704"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010023\u20106368\u20105"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202425006"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407940"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE01395E"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.324"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2021.02.026"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC01571A"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401867"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71570","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71570","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71570","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T14:58:18Z","timestamp":1786460298000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71570"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,11]]},"references-count":56,"alternative-id":["10.1002\/chem.71570"],"URL":"https:\/\/doi.org\/10.1002\/chem.71570","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,11]]},"assertion":[{"value":"2026-06-21","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-01","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71570"}}