{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T05:20:33Z","timestamp":1787721633448,"version":"build-2784847793"},"reference-count":47,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T00:00:00Z","timestamp":1787616000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T00:00:00Z","timestamp":1787616000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFB3809500"],"award-info":[{"award-number":["2023YFB3809500"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Lithium\u2013sulfur batteries are considered one of the most promising next\u2010generation energy storage systems owing to their high theoretical energy density and natural abundance of sulfur. However, their practical application is severely hampered by the polysulfide shuttle effect and sluggish conversion kinetics. Herein, a two\u2010dimensional MoS\n                    <jats:sub>2<\/jats:sub>\n                    \/MXene heterojunction composite (MMS) is rationally designed via one\u2010step hydrothermal growth of vertically aligned MoS\n                    <jats:sub>2<\/jats:sub>\n                    nanoflowers on conductive Ti\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    T\n                    <jats:sub>x<\/jats:sub>\n                    MXene substrates. This unique architecture integrates the high conductivity of MXene with abundant catalytic edge sites of MoS\n                    <jats:sub>2<\/jats:sub>\n                    , forming a tightly coupled heterointerface with 1T\/2H mixed\u2010phase MoS\n                    <jats:sub>2<\/jats:sub>\n                    that synergistically enables physical confinement, chemical adsorption, and electrocatalytic conversion of polysulfides. When employed as a functional coating on polypropylene separators, MMS@PP exhibits enhanced electrolyte wettability, high ionic conductivity (1.476 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), and a lithium\u2010ion transference number of 0.49. Consequently, Li\u2013S batteries incorporating MMS@PP deliver a high specific capacity of 1294.1 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 C with low polarization (161\u00a0mV), excellent rate capability (5 C), and outstanding cycling stability with 89.1% capacity retention after 100 cycles at 0.2 C. This work provides a rational heterojunction design strategy for developing multifunctional separators toward high\u2010performance Li\u2013S batteries.\n                  <\/jats:p>","DOI":"10.1002\/chem.71592","type":"journal-article","created":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T04:38:17Z","timestamp":1787719097000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Vertically Aligned MoS\n                    <sub>2<\/sub>\n                    \/MXene Heterojunction as a Bifunctional Separator Coating for Suppressing Shuttle Effect and Enhancing Li\n                    <sup>+<\/sup>\n                    Transport in Li\u2013S Batteries"],"prefix":"10.1002","author":[{"given":"Tao","family":"Wu","sequence":"first","affiliation":[{"name":"College of Aerospace Engineering Chongqing University  Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunxia","family":"Liu","sequence":"additional","affiliation":[{"name":"Chongqing Industry Polytechnic University  Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Chang","sequence":"additional","affiliation":[{"name":"College of Materials and Environmental Engineering Chizhou University  Chizhou Anhui China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7826-9307","authenticated-orcid":false,"given":"Ronghua","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering and National Engineering Research Center for Magnesium Alloys Chongqing University  Chongqing China"},{"name":"Chongqing Institute of New Energy Storage Materials and Equipment Mingyue Lake Laboratory  Chongqing 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