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The reaction of (NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )H\n                    <jats:sub>3<\/jats:sub>\n                    with trimethylaluminium affords bimetallic complex [Al\n                    <jats:sub>2<\/jats:sub>\n                    Me\n                    <jats:sub>3<\/jats:sub>\n                    (NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )] which reacts with iodine to form the corresponding monometallic complex [Al(NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )(I)\n                    <jats:sub>2<\/jats:sub>\n                    ]. The reduction of [Al(NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )(I)\n                    <jats:sub>2<\/jats:sub>\n                    ] with sodium and potassium containing reducing agents was explored. From potassium reductions, only complexes K[Al(NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )(I)] (from K\/KI) and [Al(NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )(TMEDA)] (from KC\n                    <jats:sub>8<\/jats:sub>\n                    \/TMEDA, TMEDA =\n                    <jats:italic>N,N,N\u2019,N\u2019<\/jats:italic>\n                    \u2010tetramethyl ethylenediamine) could be isolated. In contrast, aluminium(III) hydride [Na(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    )][Al(NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )(H)] was formed from reduction of [Al(NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )(I)\n                    <jats:sub>2<\/jats:sub>\n                    ] in benzene with excess sodium metal (mirror). This complex is unstable and readily decomposes in the presence of ethers, such as 2.2.2\u2010cryptand, to give the aluminium(III) complex [Al(NNN\n                    <jats:sup>TCHP<\/jats:sup>\n                    )(2.2.2\u2010cryptand)].\n                  <\/jats:p>","DOI":"10.1002\/chem.71614","type":"journal-article","created":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T14:09:42Z","timestamp":1787321382000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and Reduction of Super\u2010Bulky Bis(anilido)acridanide Aluminium Complexes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5383-3220","authenticated-orcid":false,"given":"Matthew J.","family":"Evans","sequence":"first","affiliation":[{"name":"School of Chemistry Monash University Clayton Victoria Australia"},{"name":"College of Science and Engineering Flinders University  Adelaide South Australia Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9761-6631","authenticated-orcid":false,"given":"Joseph M.","family":"Parr","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University Clayton Victoria Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7269-1045","authenticated-orcid":false,"given":"Cameron","family":"Jones","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University Clayton Victoria 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