{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T14:48:33Z","timestamp":1787323713789,"version":"build-2736575974"},"reference-count":49,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22571168"],"award-info":[{"award-number":["22571168"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFA1507200"],"award-info":[{"award-number":["2023YFA1507200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The electrochemical reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to ethylene (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ) offers an attractive route for carbon valorization to bulk chemicals by using sustainable energy. However, its practical application is hindered by sluggish C\u2500C coupling kinetics and poor C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    selectivity at high current densities. While hollow\u2010structured Cu\n                    <jats:sub>2<\/jats:sub>\n                    O can enrich *CO intermediates, further enhancing C\u2500C coupling on such structures remains challenging. In this context, we developed a ligand modulation strategy to tailor the catalytic properties of double\u2010shell hollow Cu\n                    <jats:sub>2<\/jats:sub>\n                    O by anchoring \u03c0\u2010conjugated 1,4\u2010bis(4\u2010pyridyl)benzene (BPB) onto the Cu\n                    <jats:sub>2<\/jats:sub>\n                    O surface via Cu\u2500N coordination bonds. Concentration\u2011dependent studies identify 10\u00a0mM BPB as the optimal balance between electronic modulation and surface accessibility. In situ ATR\u2011SEIRAS and density functional theory calculations collectively demonstrate that the electron donation from pyridinic N donors to Cu\n                    <jats:sup>+<\/jats:sup>\n                    sites promotes CO\n                    <jats:sub>2<\/jats:sub>\n                    activation and *COOH formation, while the strengthened *CO adsorption is expected to facilitate C\u2500C coupling. As a result, the optimized Cu\n                    <jats:sub>2<\/jats:sub>\n                    O\u2010BPB\u201010 catalyst delivered a C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    Faradaic efficiency (FE) of 61.6% and a total C\n                    <jats:sub>2+<\/jats:sub>\n                    FE of 85.1% at a current density of 600\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This work provides a facile and versatile ligand engineering strategy for designing high\u2010performance Cu\u2010based catalysts for practical electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction under industrially relevant conditions.\n                  <\/jats:p>","DOI":"10.1002\/chem.71617","type":"journal-article","created":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T14:12:27Z","timestamp":1787321547000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Modulation of Local Electronic Structure in Double\u2010Shell Hollow Cu\n                    <sub>2<\/sub>\n                    O via Pyridyl Ligands for Efficient CO\n                    <sub>2<\/sub>\n                    \u2010to\u2010Ethylene Conversion"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-6902-0400","authenticated-orcid":false,"given":"Xiao\u2010Rong","family":"Wen","sequence":"first","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry Frontiers Science Center For New Organic Matter College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-3542-9704","authenticated-orcid":false,"given":"Xin\u2010Yi","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry Frontiers Science Center For New Organic Matter College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-1774-5836","authenticated-orcid":false,"given":"Shan\u2010Shan","family":"Chen","sequence":"additional","affiliation":[{"name":"State 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