{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T06:59:12Z","timestamp":1790751552985,"version":"4.1.0"},"reference-count":50,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>While halogen bonding has been employed for the construction of organic frameworks, no metal\u2010organic frameworks (MOFs) with additional halogen bonding functionality are known to date. Here, we present a suitable ligand for such systems, which combines a polyiodinated and \u2010fluorinated terphenyl core with two carboxyl groups for metal coordination. Depending on the crystallization conditions, the ligand assembles with bivalent zinc cations into three distinct crystalline systems, either: (i) a metal\u2010containing hydrogen\u2010bonded organic framework; (ii) a MOF; or (iii) one\u2010dimensional metal\u2010organic chains with intermolecular halogen bonding and hydrogen bonding between adjacent chains. The 1D chains (iii) are obtained when using carbon disulfide as the crystallization medium, underscoring the potential of uncommon solvents in the design of structurally diverse crystalline materials formed from different supramolecular interactions. This study showcases the role of noncovalent interactions and halogen chemistry in directing crystal packing and highlights the challenges associated with the preparation of porous halogen bonding MOFs.<\/jats:p>","DOI":"10.1002\/chem.71620","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T06:27:24Z","timestamp":1790749644000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Towards Halogen Bonding MOFs: Networking With a Polyiodinated and Perfluorinated Terphenyl Ligand and Divalent Zinc"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9454-2884","authenticated-orcid":false,"given":"Elad","family":"Gaver","sequence":"first","affiliation":[{"name":"Department of Molecular Chemistry and Materials Science Weizmann Institute of Science Rehovot Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christoph J.","family":"Vonnemann","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t F\u00fcr Chemie und Biochemie Ruhr\u2010Universit\u00e4t Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julian","family":"Stoesser","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t F\u00fcr Chemie und Biochemie Ruhr\u2010Universit\u00e4t Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jennifer A. E.","family":"R\u00fchle","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t F\u00fcr Chemie und Biochemie Ruhr\u2010Universit\u00e4t Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9774-2358","authenticated-orcid":false,"given":"Mark A.","family":"Iron","sequence":"additional","affiliation":[{"name":"Department of Chemical Research Support Weizmann Institute of Science  Rehovot Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linda J. W.","family":"Shimon","sequence":"additional","affiliation":[{"name":"Department of Chemical Research Support Weizmann Institute of Science  Rehovot Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michal","family":"Lahav","sequence":"additional","affiliation":[{"name":"Department of Molecular Chemistry and Materials Science Weizmann Institute of Science Rehovot Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4125-159X","authenticated-orcid":false,"given":"Stefan M.","family":"Huber","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t F\u00fcr Chemie und Biochemie Ruhr\u2010Universit\u00e4t Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4102-4220","authenticated-orcid":false,"given":"Milko E.","family":"van der Boom","sequence":"additional","affiliation":[{"name":"Department of Molecular Chemistry and Materials Science Weizmann Institute of Science Rehovot Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,29]]},"reference":[{"key":"e_1_2_7_2_1","first-page":"1","article-title":"Advances and Applications of Metal\u2010organic Frameworks (MOFs) in Emerging Technologies: A Comprehensive Review","volume":"8","author":"Li D.","year":"2024","journal-title":"Glob Challenges"},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","first-page":"44507","DOI":"10.1021\/acsomega.2c05310","article-title":"Review on Metal\u2010organic Framework Classification, Synthetic Approaches, and Influencing Factors: Applications in Energy, Drug Delivery, and Wastewater Treatment","volume":"7","author":"Yusuf V. F.","year":"2022","journal-title":"ACS Omega"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.4028\/www.scientific.net\/AMM.316\u2010317.946"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3055639"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature03852"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1067208"},{"key":"e_1_2_7_9_1","unstructured":"Nobel Prize in Chemistry (2025) https:\/\/www.nobelprize.org\/prizes\/chemistry\/2025\/summary\/."},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp067906x"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm803218f"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac197127040647"},{"key":"e_1_2_7_13_1","doi-asserted-by":"crossref","DOI":"10.1002\/9780470771723.ch2","volume-title":"Molecular Interactions Involving Organic Halides","author":"Dumas J. M.","year":"1983"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00484"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CE01629J"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja5066587"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwaa170"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg400988m"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500674c"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja036994l"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521\u20103773(19990816)38:16<2433::AID\u2010ANIE2433>3.0.CO;2\u2010D"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg0501433"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301351"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8NJ00962G"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC09163A"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201502043"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CE00973K"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar5001555"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja509705f"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201904322"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QO01593A"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102448"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CE01140D"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.09.035"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.3c01427"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202408428"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA06144B"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b01163"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b02267"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1055\/a\u20101647\u20106973"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp00054k"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200400946"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie901182y"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ef950219c"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1139\/v66\u2010216"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576719014092"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1155\/2017\/7520640"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00037"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3RA04940J"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00173a008"},{"key":"e_1_2_7_51_1","unstructured":"Deposition numbers 2446211 (forL2') 2446210 (forL2) 2493684 (forL3) 2446209 (forC1) 2446207 (forC2) and 2446208 (forC3) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71620","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71620","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71620","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T06:27:28Z","timestamp":1790749648000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71620"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,29]]},"references-count":50,"alternative-id":["10.1002\/chem.71620"],"URL":"https:\/\/doi.org\/10.1002\/chem.71620","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,29]]},"assertion":[{"value":"2026-05-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-04","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71620"}}