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Visible\u2010light photocatalysis has emerged as a powerful strategy that overcomes these limitations by leveraging single\u2010electron transfer to highly reactive radical intermediates under mild conditions. This review provides a mechanistically guided overview of recent advances in photocatalytic functionalization of aryl chlorides and fluorides, encompassing oxidative and reductive radical activation, radical\u2013polar crossover, homolytic aromatic substitution, and synergistic photoredox\/transition\u2010metal catalysis.\n                  <\/jats:p>","DOI":"10.1002\/chem.71626","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T13:55:00Z","timestamp":1788011700000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Visible\u2010Light Photocatalytic Functionalization of Aryl Chlorides and Fluorides"],"prefix":"10.1002","author":[{"given":"Biao","family":"Chen","sequence":"first","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanyan","family":"Liao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinqiang","family":"Fang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,29]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"crossref","first-page":"3555","DOI":"10.1055\/a-2344-5677","article-title":"Latest Developments on Palladium\u2010 and Nickel\u2010Catalyzed Cross\u2010Couplings Using Aryl Chlorides: Suzuki\u2013Miyaura and Buchwald\u2013Hartwig Reactions","volume":"56","author":"Sen A.","year":"2024","journal-title":"Synthesis"},{"key":"e_1_2_9_3_1","doi-asserted-by":"crossref","first-page":"308","DOI":"10.1039\/B711844A","article-title":"Understanding Organofluorine Chemistry. 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