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Owing to their strong \u03c3\u2010donating ability and extreme steric bulk, these ligands stabilize highly reactive, low\u2010coordinate metal centers and enable access to unusual bonding motifs and electronic structures. This review summarizes advances in the synthesis, structure, bonding, and reactivity of group 3\u201310 metal\u2013silyl complexes prepared using persilylated and related silyl anions. Synthetic strategies, particularly salt metathesis with metal halide precursors and related methodologies, are highlighted as versatile routes to both early and late transition metal systems. Recent developments in multidentate and chelating oligosilyl ligands are also emphasized for their role in controlling coordination environments and enabling unique geometries. The reactivity of these complexes, including insertion reactions, \u03c3\u2010bond metathesis, and small\u2010molecule activation, is discussed alongside their catalytic applications in polymerization, hydrosilylation, and hydrogenation. Overall, persilylated silyl ligands provide a versatile platform for advancing organometallic chemistry and catalytic science.<\/jats:p>","DOI":"10.1002\/chem.71644","type":"journal-article","created":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T06:59:05Z","timestamp":1788332345000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Persilylated and Related Silyl Anion\u2010Induced Synthesis of Group 3\u201310 Metal\u2013Silyl Complexes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8954-181X","authenticated-orcid":false,"given":"Yusuke","family":"Sunada","sequence":"first","affiliation":[{"name":"Institute of Industrial Science The University of Tokyo  Meguro\u2010ku Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,1]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/0470025107.ch24"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00559"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900359c"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9701086"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1080\/02603594.2020.1737026"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/d3cs00893b"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2026.1804159"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1007\/bf01127889"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/om049862p"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/0470857250.ch35"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202400162"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/s0010\u20108545(01)00422\u20102"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u2010328x(95)00530\u20104"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.78.1887"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00417"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1093\/bulcsj\/uoaf092"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010\u20108545(91)84025\u2010z"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1055\/a\u20102235\u20104987"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/0470857250.ch14"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/430_2013_104"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/s0065\u20103055(08)60425\u20106"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.08.020"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010\u20108545(95)90218\u2010x"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-801981-8.00007-1"},{"key":"e_1_2_7_26_1","volume-title":"Organometallic Compounds of Low\u2010coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds","author":"Lee V. 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