{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T11:21:35Z","timestamp":1789125695971,"version":"build-2803163510"},"reference-count":55,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T00:00:00Z","timestamp":1789084800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T00:00:00Z","timestamp":1789084800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22273037"],"award-info":[{"award-number":["22273037"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"ABSTRACT<\/jats:title>\n \n The crystallization pathways of metal phosphonate frameworks (MPFs) remain poorly understood because the strong coordination ability of phosphonate ligands often leads to rapid precipitation, making the isolation of transient intermediates challenging. Herein, we report two 3D Cu\u2010based MPFs, [Cu\n 2<\/jats:sub>\n (amp\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n )]\u00b72H\n 2<\/jats:sub>\n O\u00b7DMF (\n Cu\u20103D<\/jats:bold>\n ) and [Cu\n 2<\/jats:sub>\n (INA)\n 2<\/jats:sub>\n (amp\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n )(H\n 2<\/jats:sub>\n O)\n 2<\/jats:sub>\n ] (\n Cu\u2010INA\u20103D<\/jats:bold>\n ), where amp\n 2<\/jats:sub>\n H\n 4<\/jats:sub>\n is photodimerized 9\u2010anthracenemethylphosphonic acid and INAH is isonicotinic acid. By shortening the reaction time, we isolated a metastable intermediate, [Cu\n 2<\/jats:sub>\n (INA)\n 2<\/jats:sub>\n (amp\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n )]\u00b72H\n 2<\/jats:sub>\n O (\n Cu\u2010INA\u20102D<\/jats:bold>\n ), which can gradually transform into the thermodynamically more stable\n Cu\u2010INA\u20103D<\/jats:bold>\n phase via reconstruction of the Cu\u2013PO\n 3<\/jats:sub>\n connectivity and reorganization of the {Cu(INA)} chains. The crystals of\n Cu\u2010INA\u20102D<\/jats:bold>\n can undergo solvent\u2010assisted cleavage to yield an accordion\u2010like morphology. Further, thermal de\u2010dimerization of the dianthracene units in\n Cu\u20103D<\/jats:bold>\n and\n Cu\u2010INA\u20103D<\/jats:bold>\n induces framework transformation, generating new phases containing anthracene moieties. We studied the photothermal properties of\n Cu\u20103D<\/jats:bold>\n ,\n Cu\u2010INA\u20103D<\/jats:bold>\n and their de\u2010dimerized products. All exhibited near\u2010infrared (NIR) photothermal responses under 808\u00a0nm laser irradiation. Benefiting from its photothermal conversion capability and the redox activity of Cu\n II<\/jats:sup>\n centers,\n Cu\u2010INA\u20103D<\/jats:bold>\n was employed to serve as a photothermally driven catalyst for pyrrole polymerization. These findings provide insight into the crystallization mechanism of copper diphosphonate frameworks and demonstrate the potential of dianthracene\u2010based MPFs as multifunctional photothermal materials.\n <\/jats:p>","DOI":"10.1002\/chem.71667","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T11:02:25Z","timestamp":1789124545000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Copper Diphosphonate Frameworks Incorporating Dianthracene: Capture of a Metastable Intermediate, Framework Transformation, and Near\u2010Infrared Photothermal Properties"],"prefix":"10.1002","author":[{"given":"Ran","family":"Gao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry School of Chemistry Nanjing University Nanjing P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian\u2010Qian","family":"Su","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry School of Chemistry Nanjing University Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye\u2010Hui","family":"Qin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry School of Chemistry Nanjing University Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4437-1105","authenticated-orcid":false,"given":"Li\u2010Min","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry School of Chemistry Nanjing University Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,11]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"crossref","first-page":"1578","DOI":"10.1038\/s41467-025-55999-4","article-title":"Direct Synthesis of a Semiconductive Doublehelical Phosphorus Allotrope in a Metal\u2010organic Framework","volume":"16","author":"Sapchenko S. 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