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However, successful 1D Th alignment is difficult. To date, template\u2010directed 1D Th alignment has been achieved through strong host\u2013guest interactions, but this results in a parallel\u2010stacked array that is unsuitable for pre\u2010organized polymerization. Herein, we report fabrication of a flexible zigzag lanthanide mesh framework (TUS\u2010Eu\u20106) that enabled 1D crystallization of Th liquid through spontaneous self\u2010interactions within adaptable 1D pores [(Th)\n                    <jats:sub>\n                      <jats:italic>m<\/jats:italic>\n                    <\/jats:sub>\n                    \u2282TUS\u2010Eu\u20106]. The 1D Th crystal structure was directly determined by x\u2010ray diffraction and revealed a T\u2010shaped configuration suitable for pre\u2010organized polymerization and oligomerization. Confined oxidative oligomerization of the inner 1D Th crystals occurred upon immersion of the (Th)\n                    <jats:sub>\n                      <jats:italic>m<\/jats:italic>\n                    <\/jats:sub>\n                    \u2282TUS\u2010Eu\u20106 crystals in a Fe(ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    \u00b7\n                    <jats:italic>n<\/jats:italic>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    O aqueous solution. TUS\u2010Eu\u20106 changed the pore shape and volume in crystalline\u2010state through solvent\u2010ligand exchange and exhibited excellent luminescent performance because of the antenna effects of its\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010diketonate ligands.\n                  <\/jats:p>","DOI":"10.1002\/chem.71685","type":"journal-article","created":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T10:10:06Z","timestamp":1789467006000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Flexible Zigzag Lanthanide Mesh Frameworks for One\u2010Dimensional Thiophene Crystallization and Oligomerization"],"prefix":"10.1002","author":[{"given":"Kotaro","family":"Yakuwa","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry Tokyo University of Science  Shinjyuku\u2010ku Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-7929-8868","authenticated-orcid":false,"given":"Naoto","family":"Matsumoto","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Tokyo University of Science  Shinjyuku\u2010ku Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1117-7904","authenticated-orcid":false,"given":"Junpei","family":"Yuasa","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Tokyo University of Science  Shinjyuku\u2010ku Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,15]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14044"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00078"},{"key":"e_1_2_6_4_1","volume-title":"Molecular mechanisms of Photosynthesis","author":"Blankenship R. 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