{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T05:06:41Z","timestamp":1790140001494,"version":"4.0.1"},"reference-count":39,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22422509"],"award-info":[{"award-number":["22422509"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["T2441002"],"award-info":[{"award-number":["T2441002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22535007"],"award-info":[{"award-number":["22535007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22371288"],"award-info":[{"award-number":["22371288"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["GJTD\u20102020\u201002"],"award-info":[{"award-number":["GJTD\u20102020\u201002"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["22Z40140"],"award-info":[{"award-number":["22Z40140"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"ABSTRACT<\/jats:title>\n \n Introduction of trialkylsilylethynyl groups to polycyclic aromatic hydrocarbon (PAH) is one effective strategy to improve the solubility and tune the packing modes. Based on our previously reported non\u2010benzenoid PAH, dicycloheptatrienerubicene (DHR), we developed a bromination\/borylation\/oxidation\/ alkynylation sequence to successfully introduce two trialkylsilylethynyl groups to the 2, 2\u2032\u2010positions of it. The resulting DHR derivatives, DHR\u2010TES and DHR\u2010TIPS with triethylsilylethynyl and triisopropylethynyl groups, respectively, can be solution\u2010processable, and their packing modes were tuned to be herringbone and 1D column, respectively. DHR\u2010TES shows higher mobility than DHR\u2010TIPS, reaching 0.012 and 0.094 cm\n 2<\/jats:sup>\n V\n \u2212<\/jats:sup>\n 1<\/jats:sup>\n s\n \u2212<\/jats:sup>\n 1<\/jats:sup>\n , respectively, for solution\u2010processable thin films and microcrystals of DHR\u2010TES.\n <\/jats:p>","DOI":"10.1002\/chem.71702","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T04:40:35Z","timestamp":1790138435000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solution\u2010Processable Dicycloheptatrienerubicenes With Two Trialkylsilylethynyl Groups"],"prefix":"10.1002","author":[{"given":"Liyuan","family":"Qin","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing China"},{"name":"University of Chinese Academy of Sciences Beijing China"},{"name":"Institute for Digital Molecular Analytics and 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