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The d\n                    <jats:sup>8<\/jats:sup>\n                    electronic configuration of Ni(II) ions confers unique coordination preferences, enabling the formation of robust, highly interconnected 3D architectures featuring diverse topological motifs, tunable porosity, and accessible coordinatively unsaturated open metal sites. Complemented by strong host\u2010guest interactions, pronounced magnetic anisotropy, and efficient redox activity, these structural features synergistically underpin the exceptional performance of 3D Ni\u2010carboxylate MOFs across a wide range of advanced applications. This review presents a systematic account of the development of carboxylate\u2010based 3D Ni\u2010MOFs, encompassing key synthetic methodologies, principles of structural classification, and their applications in gas adsorption and separation, heterogeneous catalysis, chemical sensing, and magnetic materials. Finally, we critically assess current challenges and outline promising future directions for the rational design and functional optimization of this compelling class of materials.\n                  <\/jats:p>","DOI":"10.1002\/chem.71720","type":"journal-article","created":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T03:18:16Z","timestamp":1790219896000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Advances and Challenges in the Development of Three\u2010Dimensional Nickel\u2010Centered Metal\u2013Organic Frameworks Engineered via Carboxylate\u2010Based Bridging Ligands"],"prefix":"10.1002","author":[{"given":"Yi","family":"Cheng","sequence":"first","affiliation":[{"name":"Hefei National Research Center for Physical Science At the Microscale, Suzhou Institute for Advanced Research, Hefei National Laboratory University of Science and Technology of China  Hefei 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