{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T12:01:00Z","timestamp":1790164860470,"version":"4.1.0"},"reference-count":36,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T00:00:00Z","timestamp":1790121600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T00:00:00Z","timestamp":1790121600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Two new benzothiazole\u2010based planar boranils (\n                    <jats:bold>B1<\/jats:bold>\n                    and\n                    <jats:bold>B2<\/jats:bold>\n                    , with acyclic and cyclic donor groups, respectively) with typical \u03c0\u2010\u03c0 interactions showed aggregation\u2010induced emission (AIE) due to integrated J\u2010aggregate bending. During enhancement of water content in DMSO solution, the AIE for\n                    <jats:bold>B2<\/jats:bold>\n                    was found slower in comparison to\n                    <jats:bold>B1<\/jats:bold>\n                    . The original green monomeric emission turned into red emission upon aggregation for both the probes. In the cell imaging studies with\n                    <jats:bold>B1<\/jats:bold>\n                    in lung cancer NCIH460 cells, aggregated red emission was observed in hydrophilic cytoplasm and monomeric green emission in hydrophobic cell membrane. However, no red AIE was observed for\n                    <jats:bold>B2<\/jats:bold>\n                    , rather green emission was enhanced in the cytoplasm after prolong incubation. The difference in red emission among the cell lines in the presence of the probes motivated an examination of cellular metabolites via LCMS\u2010MS studies. Careful analysis of the metabolic products suggested that cellular metabolism was significantly affected due to the probes. The major change in the cellular protein metabolism due to\n                    <jats:bold>B1<\/jats:bold>\n                    probe could not restrict the AIE\u2010based imaging. However, the change in lipid metabolism after\n                    <jats:bold>B2<\/jats:bold>\n                    treatment did not allow the AIE\u2010based imaging even after 6\u00a0h incubation. Cells after 48\u00a0h starvation period showed red emission from\n                    <jats:bold>B2<\/jats:bold>\n                    probe.\n                  <\/jats:p>","DOI":"10.1002\/chem.71725","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T11:12:16Z","timestamp":1790161936000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Effect of Acyclic and Cyclic Donor Groups in Boranil Partial\n                    <i>J<\/i>\n                    \u2010Aggregations in Lipid Metabolism and Bio\u2010Imaging"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-1793-7372","authenticated-orcid":false,"given":"Pushpendra","family":"Singh","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tiyasa","family":"Pathak","sequence":"additional","affiliation":[{"name":"Department of Biosciences and Bioengineering Indian Institute of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Menaka","family":"Chauhan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1943-3079","authenticated-orcid":false,"given":"Partha","family":"Roy","sequence":"additional","affiliation":[{"name":"Department of Biosciences and Bioengineering Indian Institute of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5891-951X","authenticated-orcid":false,"given":"Kalyan K.","family":"Sadhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,23]]},"reference":[{"key":"e_1_2_11_2_1","doi-asserted-by":"crossref","first-page":"10189","DOI":"10.1039\/D3CS00017F","article-title":"Aggregation\u2010induced Emission\u2010active Supramolecular Polymers: From Controlled Preparation to Applications","volume":"53","author":"Wang B.","year":"2024","journal-title":"Chemical Society Reviews"},{"key":"e_1_2_11_3_1","doi-asserted-by":"crossref","first-page":"20559","DOI":"10.1021\/acsnano.2c07263","article-title":"Tang, Insights Into Self\u2010Assembly of Nonplanar Molecules With Aggregation\u2010Induced Emission Characteristics","volume":"16","author":"Li J.","year":"2022","journal-title":"ACS Nano"},{"key":"e_1_2_11_4_1","doi-asserted-by":"crossref","first-page":"6715","DOI":"10.1039\/D3CS00251A","article-title":"Aggregation Behaviour of Pyrene\u2010Based Luminescent Materials, From Molecular Design and Optical Properties to Application","volume":"52","author":"Feng X.","year":"2023","journal-title":"Chemical Society Reviews"},{"key":"e_1_2_11_5_1","doi-asserted-by":"crossref","first-page":"12979","DOI":"10.1002\/anie.201904789","article-title":"Photoconductive Core\u2013Shell Liquid\u2010Crystals of a Perylene Bisimide J\u2010Aggregate Donor\u2013Acceptor Dyad","volume":"58","author":"Heht M.","year":"2019","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_11_6_1","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1021\/acscentsci.4c02157","article-title":"Supramolecular Engineering of Narrow Absorption Bands by Exciton Coupling in Pristine and Mixed Solid\u2010State Dye Aggregates","volume":"11","author":"Schembri T.","year":"2025","journal-title":"ACS Central Science"},{"key":"e_1_2_11_7_1","doi-asserted-by":"crossref","first-page":"642","DOI":"10.1021\/acs.accounts.0c00590","article-title":"Supramolecularly Engineered J\u2010Aggregates Based on Perylene Bisimide Dyes","volume":"54","author":"Hecht M.","year":"2021","journal-title":"Accounts of Chemical Research"},{"key":"e_1_2_11_8_1","doi-asserted-by":"crossref","first-page":"7069","DOI":"10.1021\/acs.chemrev.7b00581","article-title":"Expanded Theory of H\u2010 and J\u2010Molecular Aggregates: The Effects of Vibronic Coupling and Intermolecular Charge Transfer","volume":"118","author":"Hestand N. 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