{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T04:05:55Z","timestamp":1790741155200,"version":"4.1.0"},"reference-count":58,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22471134"],"award-info":[{"award-number":["22471134"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["63263152"],"award-info":[{"award-number":["63263152"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>The direct reductive coupling of alkenes with aldehydes offers an attractive alternative to conventional carbonyl addition using preformed organometallic reagents, yet intermolecular coupling of simple alkenes remains challenging. In this study, we report a diboron\u2010enabled nickel\u2010catalyzed reductive coupling of styrenes and related alkenes with aliphatic aldehydes to afford saturated alcohols with up to 93% yield and high linear regioselectivity. A diboron reagent\/lithium methoxide (MeOLi) combination is crucial for productive coupling and enables broad functional\u2010group tolerance. Deuterium\u2010labeling and control experiments indicate that ethanol is the predominant hydrogen source and are consistent with a nickelacycle\u2010based reductive pathway. This reaction establishes a complementary nickel\u2010catalyzed manifold for direct alkene\u2013aldehyde reductive coupling under mild conditions.<\/jats:p>","DOI":"10.1002\/chem.71743","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T03:47:18Z","timestamp":1790740038000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Diboron\u2010Enabled Nickel\u2010Catalyzed Intermolecular Reductive Coupling of Styrenes With Aldehydes"],"prefix":"10.1002","author":[{"given":"Hai\u2010Ting","family":"Yin","sequence":"first","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry College of Chemistry Frontiers Science Center for New Organic Matter Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Qing","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry College of Chemistry Frontiers Science Center for New Organic Matter Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3998-3628","authenticated-orcid":false,"given":"Li\u2010Jun","family":"Xiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry College of Chemistry Frontiers Science Center for New Organic Matter Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,29]]},"reference":[{"key":"e_1_2_8_2_1","volume-title":"Chapter \u201cReaction of Carbon Nucleophiles With Carbonyl Groups\u201d","author":"Carey F. 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