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Using organic disulfides and diphenyl diselenide as both the mediators and reactants, white phosphorus could react with amino alcohols smoothly to generate cyclic phosphoramides in moderate\u2010to\u2010good yields (34%\u201395%). This one\u2010step approach features mild reaction conditions and a simple operational process without chlorination. Mechanistic studies showed that the P\u2550O double bond in the product was formed via possible bicyclic quaternary phosphonium salt intermediates. In addition, the organic disulfides\/diselenides could be recycled without the addition of external oxidants.\n                  <\/jats:p>","DOI":"10.1002\/chem.71747","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T03:13:34Z","timestamp":1790824414000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Direct Synthesis of Cyclic Phosphoramides From White Phosphorus Prompted by Dichalcogenides"],"prefix":"10.1002","author":[{"given":"Yu","family":"Chen","sequence":"first","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering State Key Laboratory of Rare\u2010earth Materials Chemistry and Applications and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education Peking University  Beijing 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