{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T08:00:02Z","timestamp":1790841602485,"version":"4.1.0"},"reference-count":32,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The binding mode and relative position of tripodal ligands influence the charge distribution in Lindqvist\u2010type vanadium alkoxides. The stronger the delocalization of\n                    <jats:italic>d<\/jats:italic>\n                    \u2010electrons is decreased, the further shifted are the observed redox events to higher potentials. X\u2010ray crystallographic data of different {V\n                    <jats:sup>IV\/V<\/jats:sup>\n                    <jats:sub>6<\/jats:sub>\n                    (tripod)\n                    <jats:sub>2<\/jats:sub>\n                    } structures is evaluated, and valence sum calculations are used to assign oxidation states to chemically inequivalent vanadium positions in such hexanuclear aggregates. The impact of varying the charge distribution in {V\n                    <jats:sup>IV\/V<\/jats:sup>\n                    <jats:sub>6<\/jats:sub>\n                    } species is discussed by comparing reduction potentials derived from voltammetric experiments. In this way, a new group of {V\n                    <jats:sup>IV\/V<\/jats:sup>\n                    <jats:sub>6<\/jats:sub>\n                    (tripod)\n                    <jats:sub>2<\/jats:sub>\n                    } isomers is characterized and related to known\n                    <jats:italic>cis<\/jats:italic>\n                    \u2010 and\n                    <jats:italic>trans<\/jats:italic>\n                    \u2010{V\n                    <jats:sup>IV\/V<\/jats:sup>\n                    <jats:sub>6<\/jats:sub>\n                    (tripod)\n                    <jats:sub>2<\/jats:sub>\n                    } isomers.\n                  <\/jats:p>","DOI":"10.1002\/chem.71758","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T07:27:01Z","timestamp":1790839621000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Charge Distribution in Mixed\u2010Valent Lindqvist\u2010Type Vanadium Alkoxides"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-1685-1851","authenticated-orcid":false,"given":"Lagan","family":"Arya","sequence":"first","affiliation":[{"name":"Department of Chemistry The University of Alabama in Huntsville  Huntsville Alabama USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1577-1743","authenticated-orcid":false,"given":"Susanne M.","family":"Rupf","sequence":"additional","affiliation":[{"name":"Institut F\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Berlin Germany"},{"name":"Yusuf Hamied Department of Chemistry University of Cambridge  Cambridge UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-8335-915X","authenticated-orcid":false,"given":"Yogesh","family":"Shandilya","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Alabama in Huntsville  Huntsville Alabama USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Johann","family":"Spandl","sequence":"additional","affiliation":[{"name":"Institut F\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6756-2951","authenticated-orcid":false,"given":"Moritz","family":"Malischewski","sequence":"additional","affiliation":[{"name":"Institut F\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Berlin Germany"},{"name":"Department Chemie Ludwig\u2010Maximilians\u2010Universit\u00e4t M\u00fcnchen  M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7247-8781","authenticated-orcid":false,"given":"Olaf","family":"Nachtigall","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Alabama in Huntsville  Huntsville Alabama USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,1]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-662-12004-0"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35190k"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/ceur.70280"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19681010215"},{"key":"e_1_2_7_6_1","first-page":"39","volume-title":"Supramolecular Systems: Chemistry, Types and Applications","author":"Linnenberg O.","year":"2017"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390306"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja052902b"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201800041"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC05295B"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c02209"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT03822D"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00854J"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00333a002"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00038a033"},{"key":"e_1_2_7_16_1","unstructured":"Deposition numbers 1996472 (for I\u2010trans) 1996473 (for II\u2010A) and 1996474 (for II\u2010B) contain the supplementary crystallographic data for this paper. 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