{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T09:50:53Z","timestamp":1791193853881,"version":"4.1.0"},"reference-count":64,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Two new diglycolamides bearing benzyl substituents on the amide moieties\u2014N,N\u2032\u2010dibutyl\u2010N,N\u2032\u2010dibenzyldiglycolamide and N,N\u2032\u2010dibenzyl\u2010N, N\u2032\u2010diphenyldiglycolamide were synthesized. The extraction of f\u2010element cations and a number of associated metals by these compounds was also studied. A significant influence of the amide fragment structure on the extraction ability, selectivity, and composition of the extracted complexes was demonstrated. Conditions were found for the purification of An(III) and An(IV) from uranium and most fission products. The complex formation of f\u2010elements (using Nd) with the ligands under consideration was studied by spectrophotometric titration. A compound of neodymium nitrate with DBnDPhDGA, with the composition [Nd(DBnDPhDGA)\n                    <jats:sub>2<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>3<\/jats:sub>\n                    ](NO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    \u00b72C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    OH, was isolated in crystalline form, and its structure was characterized by x\u2010ray diffraction.\n                  <\/jats:p>","DOI":"10.1002\/chem.71760","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T08:52:16Z","timestamp":1791190336000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Role of the Benzyl Substituent in Binding of f\u2010Elements by Diglycolamides: A Combined Solvent Extraction, Spectroscopic, and X\u2010Ray Diffraction Study"],"prefix":"10.1002","author":[{"given":"Yu. T.","family":"Tikhomirova","sequence":"first","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences  Moscow Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S. P.","family":"Mosaleva","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences  Moscow Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"V. E.","family":"Sharov","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences  Moscow Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A. A.","family":"Sivolap","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences  Moscow Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"K. A.","family":"Lyssenko","sequence":"additional","affiliation":[{"name":"Department of Chemistry Lomonosov Moscow State University  Moscow Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A. M.","family":"Fedoseev","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences  Moscow Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G. V.","family":"Kostikova","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences  Moscow Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,5]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1146\/annurev-environ-090611-143314","article-title":"Geologic Disposal of High\u2010Level Radioactive Waste: Status, Key Issues, and Trends","volume":"37","author":"Birkholzer J.","year":"2012","journal-title":"Annual Review of Environment and Resources"},{"key":"e_1_2_9_3_1","article-title":"Challenges with Vitrification of Hanford High\u2010Level Waste (HLW) to Borosilicate Glass\u2013An Overview","volume":"4","author":"Goel A.","year":"2019","journal-title":"Journal of Non\u2010Crystalline Solids: X"},{"key":"e_1_2_9_4_1","doi-asserted-by":"crossref","first-page":"943","DOI":"10.1070\/RCR4589","article-title":"Recovery of Minor Actinides from High\u2010Level Wastes: Modern Trends","volume":"85","author":"Alyapyshev M. 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