{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T05:51:50Z","timestamp":1791352310423,"version":"4.3.1"},"reference-count":91,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T00:00:00Z","timestamp":1791244800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T00:00:00Z","timestamp":1791244800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Tin\u2010based oxides are recognized as promising high\u2010capacity anode materials for lithium\u2010ion batteries owing to their high theoretical specific capacity and favorable operating voltage. Nevertheless, their widespread practical implementation has been hindered by substantial volume fluctuations during lithiation\/delithiation processes, as well as inferior rate capability. In this work, we synthesized a tin\u2010based metal\u2013organic framework (Sn\u2010MOF) precursor at room temperature and subsequently transformed it via annealing treatment into a heterostructure Sn\u2010SnO\n                    <jats:sub>2<\/jats:sub>\n                    \/Sn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    @C composites. This self\u2010sacrificing MOF\u2010derived strategy yields a material featuring both a conductive carbon coating and an integrated SnO\n                    <jats:sub>2<\/jats:sub>\n                    \/Sn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    heterostructure, which collectively enhance electronic conductivity and mitigate volume expansion. Benefiting from the synergistic effect between the carbon matrix and the heterointerface, the anode material exhibits excellent electrochemical performance. Electrochemical tests demonstrate that the anode material presents a high reversible capacity (1242 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1C), and its first\u2010cycle coulombic efficiency reached 80.4%, a remarkable rate capability (501 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5C), and a high lithium\u2010ion diffusion coefficient. Furthermore, the electrode retains a capacity of 800 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 800 cycles at 500\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work establishes an effective heterointerface engineering approach and offers a viable design strategy for fabricating Sn\u2010based anode materials that combine long\u2010term cycling stability with high\u2010rate capability.\n                  <\/jats:p>","DOI":"10.1002\/chem.71777","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T05:49:17Z","timestamp":1791352157000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tin\u2010Based Metal\u2013Organic Framework Derived Sn\u2010SnO\n                    <sub>2<\/sub>\n                    \/Sn\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    @C With a Heterogeneous Structure as an Advanced Anode for High\u2010Performance Lithium\u2010Ion Batteries"],"prefix":"10.1002","author":[{"given":"Shikai","family":"Liu","sequence":"first","affiliation":[{"name":"High\u2010Performance Organic Optical Polymers and Advanced Manufacturing Technology, Shandong Key Laboratory of Analytical Chemistry for Life Science and Intelligent Detection, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology  Qingdao P. 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