{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T05:51:08Z","timestamp":1791352268620,"version":"4.3.1"},"reference-count":38,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T00:00:00Z","timestamp":1791244800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T00:00:00Z","timestamp":1791244800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100007928","name":"Ningbo Municipal Bureau of Science and Technology","doi-asserted-by":"publisher","award":["2023J359"],"award-info":[{"award-number":["2023J359"]}],"id":[{"id":"10.13039\/501100007928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22072170"],"award-info":[{"award-number":["22072170"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23A20125"],"award-info":[{"award-number":["U23A20125"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Mesoporous copper oxide (CuO) fabricated via mechanochemical milling was employed as a robust catalyst for the efficient synthesis of 2,5\u2010furandicarboxylic acid (FDCA) in a sodium hypochlorite (NaClO) oxidation system. We demonstrate that introducing cetyltrimethylammonium bromide (CTAB) in the mechanochemical synthesis process successfully creates mesoporosity, reduces the size of CuO nanoparticles, and modulates the ratio between surface oxygen vacancies (O\n                    <jats:sub>V<\/jats:sub>\n                    ) and lattice oxygen (O\n                    <jats:sub>L<\/jats:sub>\n                    ). Owing to its minimized particle size, enlarged pore volume, and elevated O\n                    <jats:sub>V<\/jats:sub>\n                    \/O\n                    <jats:sub>L<\/jats:sub>\n                    ratio, the CuO@0.4 CTAB catalyst delivers exceptional catalytic activity and reusability toward 5\u2010hydroxymethylfurfural (HMF) oxidation, affording a maximum FDCA yield of 95.2% under optimal reaction conditions. Furthermore, maintaining the solution pH value above 12 greatly inhibits the over\u2010oxidation of FDCA and slows the rapid consumption of NaClO during the reaction.\n                  <\/jats:p>","DOI":"10.1002\/chem.71779","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T05:25:58Z","timestamp":1791350758000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Mechanochemical Synthesis of Mesoporous Copper Oxide for the Oxidation of 5\u2010Hydroxymethylfurfural to 2,5\u2010Furandicarboxylic Acid"],"prefix":"10.1002","author":[{"given":"Peng","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"Institute of Industrial Catalysis Zhejiang University of Technology  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiquan","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hualei","family":"Hu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1076-4237","authenticated-orcid":false,"given":"Soliman I.","family":"El\u2010Hout","sequence":"additional","affiliation":[{"name":"Nanostructured Materials and Nanotechnology Department Advanced Materials Institute Central Metallurgical Research and Development Institute CMRDI  Helwan Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guojun","family":"Lan","sequence":"additional","affiliation":[{"name":"Institute of Industrial Catalysis Zhejiang University of Technology  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guowen","family":"Lu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianquan","family":"Fang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0075-7375","authenticated-orcid":false,"given":"Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9204-450X","authenticated-orcid":false,"given":"Chunlin","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biobased Polymeric Materials of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,6]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CS01234A"},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/j.jobab.2024.03.001","article-title":"Emergence of Biomass\u2010Derived Single\u2010Atom Catalysts for Platform Chemicals Production","volume":"9","author":"Loy A. C. M.","year":"2024","journal-title":"Journal of Bioresources and Bioproducts"},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","first-page":"508","DOI":"10.1016\/j.jobab.2024.09.001","article-title":"Selective Biomass Conversion Over Novel Designed Tandem Catalyst","volume":"9","author":"Azar F. Z.","year":"2024","journal-title":"Journal of Bioresources and Bioproducts"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2025.116002"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2025.116629"},{"key":"e_1_2_7_7_1","doi-asserted-by":"crossref","DOI":"10.1002\/cssc.202502033","article-title":"Green Piezo\u2010Photocatalytic Oxidation of HMF to DFF over Mn\u2010Doped Zr\/Hf\u2010Based UiO\u201066 Frameworks under Mild Conditions","volume":"19","author":"Xie H. Q.","year":"2026","journal-title":"Chemsuschem"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2019.06.033"},{"key":"e_1_2_7_9_1","doi-asserted-by":"crossref","first-page":"943","DOI":"10.3390\/polym14050943","article-title":"The Road to Bring FDCA and PEF to the Market","volume":"14","author":"Jong E.","year":"2022","journal-title":"Polymers"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8GC02680G"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09917"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5GC00157A"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.70647"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal15121120"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.5c04117"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2026.135023"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.0c00142"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2018.06.120"},{"key":"e_1_2_7_19_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.mcat.2024.113917","article-title":"Oxygen Vacancy Boosted Oxidation of 5\u2010Hydroxymethylfurfural to 2, 5\u2010Furandicarboxylic Acid Over CuCoOx","volume":"556","author":"Jiang W.","year":"2024","journal-title":"Molecular Catalysis"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202500181"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2022.118004"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.3390\/pr13072026"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202301519"},{"key":"e_1_2_7_24_1","doi-asserted-by":"crossref","first-page":"1078","DOI":"10.1016\/S1872-2067(19)63288-2","article-title":"Solid\u2010state CTAB\u2010assisted Synthesis of Mesoporous Fe3O4 and Au@ Fe3O4 by Mechanochemistry","volume":"40","author":"Zhao J. H.","year":"2019","journal-title":"Chinese Journal of Catalysis"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA03578H"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c02065"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c01587"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c18059"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2025.114105"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcrysgro.2024.127917"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs300008g"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010017\u201000366\u20107"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs200085e"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2025.178563"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11468\u2010025\u201003007\u20102"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35378D"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c04503"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.140179"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2024.05.002"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71779","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71779","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71779","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T05:25:59Z","timestamp":1791350759000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71779"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,6]]},"references-count":38,"alternative-id":["10.1002\/chem.71779"],"URL":"https:\/\/doi.org\/10.1002\/chem.71779","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,6]]},"assertion":[{"value":"2026-07-21","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-29","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71779"}}