{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T11:46:34Z","timestamp":1791891994910,"version":"4.3.4"},"reference-count":31,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T00:00:00Z","timestamp":1791849600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T00:00:00Z","timestamp":1791849600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22575090"],"award-info":[{"award-number":["22575090"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52373178"],"award-info":[{"award-number":["52373178"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52273178"],"award-info":[{"award-number":["52273178"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>A serial of three\u2010armed boron\u2010locked nonastarazines (NSAs) peripherally fused with thiazole or benzothiazole rings have been synthesized via a two\u2010step sequential reaction under mild conditions. Single\u2010crystal x\u2010ray diffraction reveals nearly planar \u03c0\u2010skeletons, with the boron atoms deviating slightly from the ring plane and the boron\u2010bound phenyl groups protruding above and below the plane to suppress \u03c0\u2013\u03c0 stacking and ensure good solubility. Compared to the previous pyridine\u2010fused NSAs, thiazole\/benzothiazole fusion significantly tunes the electronic structure. Introduction of electron\u2010donating substituents (phenyl, thienyl) at the 5\u2010 or 6\u2010position of the benzothiazole arms modulates the photoluminescence quantum yields (PLQYs) from 2.7% to 64.1%. Notably, 6\u2010substitution produces consistently higher PLQYs than 5\u2010substitution. This work expands the core chemistry of star\u2010shaped B,N\u2010doped arenes and establishes clear structure\u2013property guidelines for efficient luminescence.<\/jats:p>","DOI":"10.1002\/chem.71790","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T10:50:29Z","timestamp":1791888629000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and Photophysical Properties of Thiazole\/Benzothiazole\u2010Fused Nonastarazines: Extending the Core and Tuning Emission via Positional Substitution"],"prefix":"10.1002","author":[{"given":"Yuhong","family":"Xie","sequence":"first","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials South China University of Technology  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials South China University of Technology  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Honglin","family":"Qiu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials South China University of Technology  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials South China University of Technology  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wentao","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials South China University of Technology  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1058-4551","authenticated-orcid":false,"given":"Linlin","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials South China University of Technology  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0826-840X","authenticated-orcid":false,"given":"Zengqi","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials South China University of Technology  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,13]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11696\u2010025\u201004624\u20101"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104020(01)96845\u20100"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202305551"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00181A"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2024.125139"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4RA11559G"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04368"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b06126"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202214769"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202218839"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1557\/s43580\u2010025\u201001318\u20104"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200400380"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411861"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2017.07.058"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202402745"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201403697"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016163"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c00293"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b00335"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QO00144J"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.3c02101"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416425"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9QO00259F"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaom.4c00371"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QO02403F"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000380"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508482"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b11337"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508916"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889808042726"},{"key":"e_1_2_7_32_1","volume-title":"Gaussian 16, Revision C.01","author":"Frisch M. J.","year":"2016"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71790","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71790","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71790","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T10:50:31Z","timestamp":1791888631000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71790"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,13]]},"references-count":31,"alternative-id":["10.1002\/chem.71790"],"URL":"https:\/\/doi.org\/10.1002\/chem.71790","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,13]]},"assertion":[{"value":"2026-08-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-03","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-13","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71790"}}