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The aim of this work is to evaluate organic carbonates and other organic solvents like THF, CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, and acetonitrile as well as members of the AHD\u2010family (DMF, DMSO, etc.) as media for homogeneous asymmetric hydrogenation. For this reason cationic Rh\u2010complexes based on chiral phosphine ligands were tested in the hydrogenation of typical benchmark substrates. In several trials, significant advantages of organic carbonates were found. In contrast to DMSO, DMF and acetonitrile, in PC and BC high conversion rates and excellent enantioselectivities were usually observed. Chirality 2009. \u00a9 2009 Wiley\u2010Liss, Inc.<\/jats:p>","DOI":"10.1002\/chir.20720","type":"journal-article","created":{"date-parts":[[2009,5,19]],"date-time":"2009-05-19T17:56:05Z","timestamp":1242755765000},"page":"857-861","source":"Crossref","is-referenced-by-count":16,"title":["Organic carbonates as alternative solvents for asymmetric hydrogenation"],"prefix":"10.1002","volume":"21","author":[{"given":"Benjamin","family":"Sch\u00e4ffner","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vasyl","family":"Andrushko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jerome","family":"Bayardon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jens","family":"Holz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Armin","family":"B\u00f6rner","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2009,5,19]]},"reference":[{"key":"e_1_2_1_2_2","first-page":"352","volume-title":"Chemistry and technology of flavors and fragrances","author":"Rowe DJ","year":"2005"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470399613"},{"key":"e_1_2_1_4_2","first-page":"531","volume-title":"Biodegradable polymers for industrial applications","author":"Smith R","year":"2005"},{"key":"e_1_2_1_5_2","first-page":"556","volume-title":"Handbook of biodegradable polymers","author":"Domb AJ","year":"2005"},{"key":"e_1_2_1_6_2","series-title":"The handbook of homogeneous hydrogenation","first-page":"1648","author":"de Vries JG","year":"2007"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/0471721506.ch1"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/3527602151"},{"key":"e_1_2_1_9_2","series-title":"Phosphorus ligands in asymmetric catalysis","first-page":"1546","author":"B\u00f6rner A","year":"2008"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2007-983902"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527621194"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200700990"},{"key":"e_1_2_1_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200700990"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr950067i"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr068357u"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar010076f"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ciuz.200900468"},{"key":"e_1_2_1_17_2","unstructured":"NorikoI (Mitsubishi ChemCorp). 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