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The pioneering works in this field date back almost 20 years ago and since then extensive research has been carried out to develop efficient and selective routes to highly enantioenriched \u03b1\u2010aminoorganostannanes. The facile Sn\/Li transmetalation of these compounds by <jats:italic>n<\/jats:italic>\u2010BuLi has led to various applications in stereoselective synthesis. Selected examples using chiral \u03b1\u2010aminoorganostannanes as starting materials will be reported. Chirality, 2010. \u00a9 2010 Wiley\u2010Liss, Inc.<\/jats:p>","DOI":"10.1002\/chir.20891","type":"journal-article","created":{"date-parts":[[2010,9,15]],"date-time":"2010-09-15T20:02:27Z","timestamp":1284580947000},"page":"864-869","source":"Crossref","is-referenced-by-count":9,"title":["Preparation of enantiomerically enriched \u03b1\u2010aminoorganostannanes and their applications in stereoselective synthesis"],"prefix":"10.1002","volume":"22","author":[{"given":"Vincent","family":"Coeffard","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Isabelle","family":"Beaudet","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jean\u2010Paul","family":"Quintard","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Erwan","family":"le Grognec","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2010,9,15]]},"reference":[{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020061a"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200800604"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527629541"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00745a034"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)91484-0"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1984-30879"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)99388-4"},{"key":"e_1_2_3_9_2","series-title":"The chemistry of organolithium compounds (Patai Series)","first-page":"997","author":"Gawley RE","year":"2004"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja044354s"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00022a065"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00060a011"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1998-1891"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(97)10031-4"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0690(200004)2000:7<1297::AID-EJOC1297>3.0.CO;2-L"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00034a007"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)60055-2"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo0161734"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2003.12.080"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol035702i"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00069a066"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(02)00154-5"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja066183s"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo0155658"},{"key":"e_1_2_3_25_2","series-title":"The chemistry of organolithium compounds (Patai Series)","first-page":"1055","author":"Christoph G","year":"2004"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00025a066"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9538804"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo9700080"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19981002)37:18<2522::AID-ANIE2522>3.0.CO;2-T"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)73050-4"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(95)00369-N"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/om034267t"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200400202"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200400203"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2005.11.070"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo900223k"},{"key":"e_1_2_3_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9500038"},{"key":"e_1_2_3_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(00)00149-6"},{"key":"e_1_2_3_39_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2009.06.003"},{"key":"e_1_2_3_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/0957-4166(94)80061-8"},{"key":"e_1_2_3_41_2","first-page":"4151","article-title":"Precursors of chiral \u03b1\u2010amino anions: an improved synthesis of chiral N\u2010(\u03b1\u2010tributylstannylorgano)oxazolidin\u20102\u2010ones derived from (R)\u2010 or (S)\u2010phenylglycinol","author":"Coeffard V","year":"2006","journal-title":"Synthesis"},{"key":"e_1_2_3_42_2","unstructured":"JeanjeanF. 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