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The structural variations were placed on an aliphatic heterocycle (six\u2010 or seven\u2010member rings) and on the carbamate function (methyl or<jats:italic>t<\/jats:italic>\u2010butyl). Their separation was achieved on a commercial cellulose<jats:italic>tris<\/jats:italic>\u2010(3,5\u2010dimethylphenylcarbamate) stationary phase (Lux Cellulose\u20101, Phenomenex) in supercritical fluid chromatography (SFC). The effects of molecular structure on SFC retention and enantioresolution were studied. Among these eight pairs of enantiomers, some reversal of elution order between similar compounds was observed. The effect of changing the organic solvent (methanol and ethanol) and its proportion (between 5 and 40%) in the mobile phase was investigated. Retention data were collected over the temperature range 0\u201350 \u00b0C, and the results interpreted from thermodynamic aspects. Chirality, 2013. \u00a9 2013 Wiley Periodicals, Inc.<\/jats:p>","DOI":"10.1002\/chir.22133","type":"journal-article","created":{"date-parts":[[2013,3,7]],"date-time":"2013-03-07T08:16:52Z","timestamp":1362644212000},"page":"230-237","source":"Crossref","is-referenced-by-count":13,"title":["Enantiomeric Separation of Original Heterocyclic Organophosphorus Compounds in Supercritical Fluid Chromatography"],"prefix":"10.1002","volume":"25","author":[{"given":"Caroline","family":"West","sequence":"first","affiliation":[{"name":"Institut de Chimie Organique et Analytique (ICOA) Universit\u00e9 d'Orl\u00e9ans, UMR CNRS 7311 B.P. 6759, rue de Chartres 45067 Orl\u00e9ans Cedex 2 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Monika","family":"Cieslikiewicz\u2010Bouet","sequence":"additional","affiliation":[{"name":"Institut de Chimie Organique et Analytique (ICOA) Universit\u00e9 d'Orl\u00e9ans, UMR CNRS 7311 B.P. 6759, rue de Chartres 45067 Orl\u00e9ans Cedex 2 France"},{"name":"Department of Organic Chemistry Jagiellonian University R. 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