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Therefore, we developed a method for the assay of <jats:sc>l<\/jats:sc>\u2010 and <jats:sc>d<\/jats:sc>\u2010glucose, based on molecular recognition of <jats:sc>l<\/jats:sc>\u2010 and <jats:sc>d<\/jats:sc>\u2010glucose. While for <jats:sc>d<\/jats:sc>\u2010glucose there are many methods to assess its quantity, the <jats:sc>l<\/jats:sc>\u2010enantiomer is not routinely detected by standard methods. Two stochastic microsensors based on the immobilization of Copper(II)phthalocyanine and Ni(II)phthalocyanine, in natural diamond powder, were proposed for the enantioanalysis of glucose. The proposed methods proved to have high sensitivities and were able to be used for determination of concentrations as low as 2.5\u00a0pg\u00a0mL<jats:sup>\u22121<\/jats:sup> for <jats:sc>d<\/jats:sc>\u2010glucose and as low as 2.5\u00a0fg\u00a0mL<jats:sup>\u22121<\/jats:sup> for <jats:sc>l<\/jats:sc>\u2010glucose. The enatioanalysis was performed with good results in whole blood samples collected from diabetic patients.<\/jats:p>","DOI":"10.1002\/chir.22843","type":"journal-article","created":{"date-parts":[[2018,3,2]],"date-time":"2018-03-02T13:12:39Z","timestamp":1519996359000},"page":"680-685","source":"Crossref","is-referenced-by-count":9,"title":["Molecular enantiorecognition of <scp>l<\/scp>\u2010glucose and <scp>d<\/scp>\u2010glucose in whole blood samples"],"prefix":"10.1002","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8244-2483","authenticated-orcid":false,"given":"Raluca\u2010Ioana","family":"Stefan\u2010van Staden","sequence":"first","affiliation":[{"name":"Laboratory of Electrochemistry and PATLAB Bucharest National Institute of Research for Electrochemistry and Condensed Matter  Bucharest Romania"},{"name":"Faculty of Applied Chemistry and Materials Science Polytechnic University Bucharest  Bucharest Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Grigorina","family":"Mitrofan","sequence":"additional","affiliation":[{"name":"Faculty of Applied Chemistry and Materials Science Polytechnic University Bucharest  Bucharest Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,3,2]]},"reference":[{"issue":"1","key":"e_1_2_6_2_1","first-page":"1","article-title":"Diabetes voice","volume":"63","author":"Villarroel D. 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