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Polysaccharide\u2010based chiral columns (cellulose and amylose) were used to evaluate the separation in SFC and HPLC. Time of analyses, consumption of solvent, and parameter optimization were reduced using SFC technique. The columns based on cellulose chiral stationary phase using 2\u2010propanol and ethanol as modifiers showed the best results for the enantioresolution of the (\u00b1)\u2010\u03b2\u2010hydroxy\u20101,2,3\u2010triazoles by SFC analyses. These techniques were applied to evaluate the selectivity of biocatalytic reduction of \u03b2\u2010keto\u20101,2,3\u2010triazoles by marine\u2010derived fungus <jats:italic>Penicillium citrinum<\/jats:italic> CBMAI 1186 to obtain the (\u00b1)\u2010\u03b2\u2010hydroxy\u20101,2,3\u2010triazoles.<\/jats:p>","DOI":"10.1002\/chir.22851","type":"journal-article","created":{"date-parts":[[2018,4,25]],"date-time":"2018-04-25T14:42:05Z","timestamp":1524667325000},"page":"890-899","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Enantioselective separation of (\u00b1)\u2010\u03b2\u2010hydroxy\u20101,2,3\u2010triazoles by supercritical fluid chromatography and high\u2010performance liquid chromatography"],"prefix":"10.1002","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0751-2685","authenticated-orcid":false,"given":"Nat\u00e1lia","family":"Alvarenga","sequence":"first","affiliation":[{"name":"Laborat\u00f3rio de Qu\u00edmica Org\u00e2nica e Biocat\u00e1lise, Instituto de Qu\u00edmica de S\u00e3o Carlos Universidade de S\u00e3o Paulo  S\u00e3o Carlos SP Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andr\u00e9 L.M.","family":"Porto","sequence":"additional","affiliation":[{"name":"Laborat\u00f3rio de Qu\u00edmica Org\u00e2nica e Biocat\u00e1lise, Instituto de Qu\u00edmica de S\u00e3o Carlos Universidade de S\u00e3o Paulo  S\u00e3o Carlos SP Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3657-2620","authenticated-orcid":false,"given":"Juliana Cristina","family":"Barreiro","sequence":"additional","affiliation":[{"name":"Laborat\u00f3rio de Qu\u00edmica Org\u00e2nica e 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