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Their ability in recognition and signal amplification of chiral substrates is because of the setup of the ligand around the metal in a propeller shape. Within this subject, we have recently reported tris(2\u2010pyridylmethyl)amine\u2010 and triphenolamine\u2010based complexes for the determination of the enantiomeric excess of various substrates. Herein, we show the versatility of the zinc tris(2\u2010pyridylmethyl)amine\u2010based stereodynamic probe by performing a detailed study of the imine formation process, by the extension of the sensing capabilities to other chiral compounds. A principal component analysis study of the system together with TD\u2010DFT studies highlights the molecular origin of the observed chiroptical properties.<\/jats:p>","DOI":"10.1002\/chir.23064","type":"journal-article","created":{"date-parts":[[2019,3,19]],"date-time":"2019-03-19T19:17:16Z","timestamp":1553023036000},"page":"375-383","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Extending substrate sensing capabilities of zinc tris(2\u2010pyridylmethyl)amine\u2010based stereodynamic probe"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9921-5252","authenticated-orcid":false,"given":"Francesca A.","family":"Scaramuzzo","sequence":"first","affiliation":[{"name":"Dipartimento di Scienze Chimiche Universit\u00e0 degli Studi di Padova  Padova 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