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We have found that the compounds of the above series can crystallize as various diastereomers by the nitrogen atom, the relative configuration of the nitrogen atom determining the relative supramolecular configuration of the newly formed chiral sulfur atom. The paper presents a stereochemical transformation, which we have called \u201cdouble crystallization\u2010induced diastereomerization.\u201d<\/jats:p>","DOI":"10.1002\/chir.23316","type":"journal-article","created":{"date-parts":[[2021,5,15]],"date-time":"2021-05-15T08:35:57Z","timestamp":1621067757000},"page":"409-420","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["From classical to supramolecular dynamic stereochemistry: Double crystallization\u2010induced diastereomerization of thiazine sulfonamide"],"prefix":"10.1002","volume":"33","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9614-5092","authenticated-orcid":false,"given":"Olga A.","family":"Lodochnikova","sequence":"first","affiliation":[{"name":"A.E. Arbuzov Institute of Organic and Physical Chemistry Kazan Scientific Center, Russian Academy of Sciences Kazan Russian Federation"},{"name":"A.M. Butlerov Institute of Chemistry Kazan Federal University Kazan Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9770-196X","authenticated-orcid":false,"given":"Daria P.","family":"Gerasimova","sequence":"additional","affiliation":[{"name":"A.E. Arbuzov Institute of Organic and Physical Chemistry Kazan Scientific Center, Russian Academy of Sciences Kazan Russian Federation"},{"name":"A.M. Butlerov Institute of Chemistry Kazan Federal University Kazan Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9430-7761","authenticated-orcid":false,"given":"Vitaly V.","family":"Plemenkov","sequence":"additional","affiliation":[{"name":"A.M. 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