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A preparatively easy and efficient protocol for resolution of the <jats:italic>N<\/jats:italic>\u2010benzoylamino alcohol is described. Using a 250\u2009\u00d7\u200920\u2009mm (L\u2009\u00d7\u2009ID) Chiralpak\u00ae IA column, and the appropriate mixture of <jats:italic>n<\/jats:italic>\u2010hexane\/ethanol\/chloroform as eluent, both enantiomers of <jats:italic>N<\/jats:italic>\u2010benzoylamino alcohol <jats:bold>3<\/jats:bold> are obtained with &gt;99% enantiomeric excess (ee) by successive injections of a solution of the racemic sample in chloroform. The obtained axially chiral vicinal amino alcohol is used to synthesize structurally novel bisoxazoline ligands in high yields.<\/jats:p>","DOI":"10.1002\/chir.23475","type":"journal-article","created":{"date-parts":[[2022,5,25]],"date-time":"2022-05-25T01:05:27Z","timestamp":1653440727000},"page":"1140-1150","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, resolution, and absolute configuration determination of a vicinal amino alcohol with axial chirality. 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