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It is now evident that beams of light with a twisted wavefront, known as optical vortices, can also interact with chiral matter with a specificity determined by relative handedness. Exploring this chiral sensitivity of vortex light in its interactions with matter requires careful consideration of the symmetry properties that engage in such processes. Most of the familiar measures of chirality are directly applicable to either matter, or to light itself\u2014but only to one or the other. To elicit the principles that determine the viability of distinctly optical vortex\u2010based forms of chiral discrimination invites a more universal approach to symmetry analysis, as is afforded by the common, fundamental physics of \n symmetry. Taking this approach supports a comprehensive and straightforward analysis to identify the mechanistic origins of vortex chiroptical interactions. Careful inspection of selection rules for absorption also elicits the principles governing any identifiable engagement with vortex structures, providing a reliable basis to ascertain the viability of other forms of enantioselective vortex interaction.<\/jats:p>","DOI":"10.1002\/chir.23604","type":"journal-article","created":{"date-parts":[[2023,7,5]],"date-time":"2023-07-05T08:05:19Z","timestamp":1688544319000},"page":"899-913","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Fundamental symmetry origins in the chiral interactions of optical vortices"],"prefix":"10.1002","volume":"35","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5903-0787","authenticated-orcid":false,"given":"David L.","family":"Andrews","sequence":"first","affiliation":[{"name":"Centre for Photonics and Quantum Science, School of Chemistry University of East Anglia  Norwich 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