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A variety of oxidants, including hydrogen peroxide (H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ), molecular oxygen (O\n                    <jats:sub>2<\/jats:sub>\n                    ), sodium hypochlorite (NaOCl),\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butyl hydroperoxide (TBHP), and iodosylbenzene (PhIO), have been employed for the oxidation reactions using different chiral transition metal complexes. This review is mainly focused on the reports of various asymmetric metal complexes as homogeneous catalysts derived from first\u2010row transition metals and chiral ligands for a range of oxidation reactions, such as epoxidation of olefins and\n                    <jats:italic>\u03b1,\u03b2<\/jats:italic>\n                    \u2010unsaturated carbonyl compounds, sulfoxidation, hydroxylation, dihydroxylation, and oxidation of spirocyclic compounds. Several chiral ligands and their metal complexes (including metals titanium, chromium, manganese, iron, cobalt, and vanadium) are utilized in asymmetric oxidation reactions, whereas asymmetric manganese complexes have been extensively used for epoxidation, hydroxylation, and oxidative kinetic resolution. This review provides a clear and broad perception for better recognizing the homogeneous asymmetric catalysts used in oxidation reactions.\n                  <\/jats:p>","DOI":"10.1002\/chir.70090","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T21:10:41Z","timestamp":1773004241000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Asymmetric Homogeneous Oxidation Reactions Catalyzed by First\u2010Row Transition Metal Complexes"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-7678-3349","authenticated-orcid":false,"given":"Geeta\u00a0Devi","family":"Yadav","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Delhi  New Delhi India"},{"name":"Department of Chemistry Kalindi College, University of Delhi  New Delhi India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7747-5595","authenticated-orcid":false,"given":"Deepa","family":"Uppal","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Delhi  New Delhi India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Priyanka","family":"Jhajharia","sequence":"additional","affiliation":[{"name":"Department of Chemistry Kirori Mal College, University of Delhi  New Delhi India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Balaram","family":"Pani","sequence":"additional","affiliation":[{"name":"Bhaskaracharya College of Applied Sciences University of Delhi  Dwarka India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5609-6556","authenticated-orcid":false,"given":"Surendra","family":"Singh","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Delhi  New Delhi India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,3,5]]},"reference":[{"key":"e_1_2_11_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-08-052349-1.00190-6"},{"key":"e_1_2_11_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-58571-5"},{"key":"e_1_2_11_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619399"},{"key":"e_1_2_11_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470584248.ch11"},{"key":"e_1_2_11_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00167"},{"key":"e_1_2_11_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/b303160h"},{"key":"e_1_2_11_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602044"},{"key":"e_1_2_11_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(94)01124-T"},{"key":"e_1_2_11_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr020471z"},{"key":"e_1_2_11_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr040700c"},{"key":"e_1_2_11_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr068367v"},{"key":"e_1_2_11_13_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-1984-30921"},{"key":"e_1_2_11_14_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-1994-25445"},{"key":"e_1_2_11_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00448a058"},{"key":"e_1_2_11_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00448a059"},{"key":"e_1_2_11_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00538a077"},{"key":"e_1_2_11_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00253a032"},{"key":"e_1_2_11_19_1","unstructured":"C. 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