{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T03:03:05Z","timestamp":1789441385293,"version":"build-2803163510"},"reference-count":30,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chirality"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Extending morphological complexity and thus achieving emergent functions remain a central challenge in materials science. Here, we report a chirality\u2010engineering strategy to tune morphological complexity and optical activity (OA) in Ag\u2010thiolate coordination polymers (ATCPs). By introducing either the opposite enantiomer D\u2010cys or the achiral 3\u2010mercaptopropionic acid (MPA) into L\u2010cys\u2010induced ATCP synthesis, we found two coinduction systems exhibiting distinct molecular mixing behaviors quantified via the entropy of mixing (EoM) of thiol precursors. The resulting morphologies, including triangular nanosheets, flower\u2010like architectures, nanoscrolls, and nanotube\u2010like assemblies, were quantitatively analyzed using a graph\u2010theoretical complexity index (CI). In the L\u2010\/D\u2010cys system, increasing EoM led to chirality cancelation, a decreased CI and an attenuated\n                    <jats:italic>g<\/jats:italic>\n                    \u2010factor, demonstrating that maximum EoM does not necessarily generate higher complexity or stronger OA. In contrast, in the L\u2010cys\/MPA system, packing mismatch transformed maximum EoM into an enhanced CI alongside OA inversion and enhancement (a maximal 8.3\u2010fold enhancement). These results reveal that the molecular role of the second thiol component, rather than EoM alone, determines whether molecular mixing suppresses or amplifies complexity and OAs. This work provides ligand\u2010modification strategy for programming complex functional coordination\u2010polymer assemblies.\n                  <\/jats:p>","DOI":"10.1002\/chir.70140","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T05:14:51Z","timestamp":1787980491000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Complexity and Optical Activity Regulation Through Chirality Engineering in Ag\u2010Thiolate Coordination Polymers"],"prefix":"10.1002","volume":"38","author":[{"given":"Yabo","family":"Fu","sequence":"first","affiliation":[{"name":"College of Chemistry Beijing Normal University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9657-6933","authenticated-orcid":false,"given":"Bing","family":"Ni","sequence":"additional","affiliation":[{"name":"College of Chemistry Beijing Normal University  Beijing 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