{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T14:47:36Z","timestamp":1792075656417,"version":"4.4.0"},"reference-count":33,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22405072"],"award-info":[{"award-number":["22405072"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chirality"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>The simple, efficient, and low\u2010cost fabrication strategies for chiral inorganic thin films are highly desirable to expand their wide applications. Herein, we develop an electrochemically assisted approach for the controllable fabrication of high\u2010performance chiral silver (Ag) films, where L\/D\u2010glutamine (Gln) molecules serve as chiral regulators to steer the asymmetric growth of Ag nanostructures. During electrochemical deposition, the L\/D\u2010Gln breaks the structural symmetry of Ag crystals, while fine\u2010tuned electrochemical parameters precisely modulate the nucleation and growth process, eliminating the structural disorder of conventional Ag films and enabling the formation of uniform and stable three\u2010dimensional hierarchical chiral architectures. The well\u2010defined chiral configuration effectively optimizes the localized surface plasmon resonance (LSPR) behavior of Ag nanomaterials and strengthens chiral plasmonic coupling interactions among hierarchical nano units. Benefiting from the synergistic effect of chiral structural engineering and enhanced plasmonic coupling, the as\u2010prepared chiral Ag films achieve remarkably amplified and stable circular dichroism (CD) responses and superior chiroptical performance. The established structure\u2013property correlation explicitly reveals the intrinsic mechanism of electrochemical regulation for improved chiroptical behaviors, clarifying the causal relationship between chiral molecular induction, structural evolution, plasmonic coupling, and optical enhancement. This work provides a facile and universal synthetic platform for high\u2010quality chiral inorganic thin films, offering great application potential in enantiomeric recognition, chiroptical modulation, and plasmonic chiral device fabrication.<\/jats:p>","DOI":"10.1002\/chir.70153","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T06:25:31Z","timestamp":1790663131000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrochemically Assisted Fabrication of Chiral Molecule Induced ag Films for Chiroptical Enhancement"],"prefix":"10.1002","volume":"38","author":[{"given":"Houliang","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory for Special Functional Materials of the Ministry of Education Henan University  Kaifeng China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Special Functional Materials of the Ministry of Education Henan University  Kaifeng China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunlei","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Laboratory for Special Functional Materials of the Ministry of Education Henan University  Kaifeng China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-1595-659X","authenticated-orcid":false,"given":"Gaoyang","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Special Functional Materials of the Ministry of Education Henan University  Kaifeng China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7495-7110","authenticated-orcid":false,"given":"Feng","family":"Bai","sequence":"additional","affiliation":[{"name":"Key Laboratory for Special Functional Materials of the Ministry of Education Henan University  Kaifeng 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