{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T12:19:24Z","timestamp":1791202764860,"version":"4.2.0"},"reference-count":36,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2005,5,11]],"date-time":"2005-05-11T00:00:00Z","timestamp":1115769600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2005,6,13]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p><jats:italic>We study the structure and dynamics of hydrogen\u2010bonded complexes of H<jats:sub>2<\/jats:sub>O\/HDO and acetone dissolved in carbon tetrachloride by probing the response of the O\uf8ffH stretching vibrations with linear mid\u2010infrared spectroscopy and femtosecond mid\u2010infrared pump\u2013probe spectroscopy. We find that the hydrogen bonds in these complexes break and reform with a characteristic time scale of \u22481 ps. These hydrogen\u2010bond dynamics are observed to play an important role in the equilibration of vibrational energy over the two O\uf8ffH groups of the H<jats:sub>2<\/jats:sub>O molecule. For both H<jats:sub>2<\/jats:sub>O and HDO, the O\uf8ffH stretching vibrational excitation relaxes with a time constant of 6.3\u00b10.3 ps, and the molecular reorientation has a time constant of 6\u00b11 ps.<\/jats:italic><\/jats:p>","DOI":"10.1002\/cphc.200400606","type":"journal-article","created":{"date-parts":[[2005,5,11]],"date-time":"2005-05-11T06:46:48Z","timestamp":1115794008000},"page":"1146-1156","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Energy Transfer in Single Hydrogen\u2010Bonded Water Molecules"],"prefix":"10.1002","volume":"6","author":[{"given":"Huib J.","family":"Bakker","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joop J.","family":"Gilijamse","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anjan 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