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However, the growth mechanism of nanotubes using the template method is seldom clarified. Herein, we present the systematic preparation of metal nanotube arrays and put forward the growth mechanism, termed current\u2010directed tubular growth (CDTG), for template\u2010based electrodeposition. There are competitive growth rates for metal atoms entering the crystal lattice, that is, v<jats:sub>\u2225<\/jats:sub> (growth rate parallel to current direction) and v<jats:sub>\u22a5<\/jats:sub> (growth rate perpendicular to current direction). Metal nanotubes can be obtained at v<jats:sub>\u2225<\/jats:sub>\u226bv<jats:sub>\u22a5<\/jats:sub>, while nanowires can be obtained at v<jats:sub>\u2225<\/jats:sub>\u2248v<jats:sub>\u22a5<\/jats:sub>. The as\u2010synthesized metal (Fe, Co, Ni) nanotubes are constructed from nonlayered materials, which are of body\u2010centered cubic iron structure, hexagonal close packed cobalt structure, and face\u2010centered cubic nickel structure, respectively. The CDTG mechanism is expected to have applications in designing and synthesizing other metal nanotubes and even compound nanotubes via template\u2010based electrodeposition technology.<\/jats:p>","DOI":"10.1002\/cphc.200500690","type":"journal-article","created":{"date-parts":[[2006,5,30]],"date-time":"2006-05-30T07:53:24Z","timestamp":1148975604000},"page":"1500-1504","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":133,"title":["Generation and Growth Mechanism of Metal (Fe, Co, Ni) Nanotube 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