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The bond lengths, dipole moments, and energies are analyzed. It is demonstrated that synergetic effects are present in the complexes. The cooperativity contribution of the dihydrogen bond is smaller than that of the N\u22c5\u22c5\u22c5HC hydrogen bond. The three\u2010body energy in systems involving different types of hydrogen bonds is larger than that in the same hydrogen\u2010bonded systems. NBO analyses indicate that orbital interaction, charge transfer, and bond polarization are mainly responsible for the cooperativity between the two types of hydrogen bonds.<\/jats:p>","DOI":"10.1002\/cphc.200800320","type":"journal-article","created":{"date-parts":[[2008,8,19]],"date-time":"2008-08-19T08:58:32Z","timestamp":1219136312000},"page":"1942-1946","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["Cooperativity between the Dihydrogen Bond and the N\u22c5\u22c5\u22c5HC Hydrogen Bond in LiH\u2013(HCN)<sub><i>n<\/i><\/sub> Complexes"],"prefix":"10.1002","volume":"9","author":[{"given":"Qing\u2010Zhong","family":"Li","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ting","family":"Hu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiu\u2010Lin","family":"An","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bao\u2010An","family":"Gong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian\u2010Bo","family":"Cheng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2008,9,9]]},"reference":[{"key":"e_1_2_6_1_2","volume-title":"An Introduction to Hydrogen Bonding","author":"Jeffrey G. 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