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High\u2010resolution STM images reveal a long\u2010range order of propeller\u2010like assemblies each of which consists of three molecules, all lying flat on the gold substrate with the cyano groups oriented parallel to the metal surface. It is demonstrated that both functional groups can act as complexation sites for metal ions from solution. Surprisingly, such arrangements still allow the metal to be deposited on top of the molecules by electrochemical reduction despite the close vicinity to the Au surface. The latter is demonstrated by angle\u2010resolved XPS which unequivocally shows that the metal indeed resides on top of the organic layer rather than underneath, despite the flat arrangement of the molecules.<\/jats:italic><\/jats:p>","DOI":"10.1002\/cphc.201000309","type":"journal-article","created":{"date-parts":[[2010,8,16]],"date-time":"2010-08-16T18:00:06Z","timestamp":1281981606000},"page":"2951-2956","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Metallization of Ultra\u2010Thin, Non\u2010Thiol SAMs with Flat\u2010Lying Molecular Units: Pd on 1, 4\u2010Dicyanobenzene"],"prefix":"10.1002","volume":"11","author":[{"given":"Felix","family":"Eberle","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Metzler","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dieter M.","family":"Kolb","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marc","family":"Saitner","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick","family":"Wagner","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hans\u2010Gerd","family":"Boyen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,8,16]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature08639"},{"key":"e_1_2_6_2_2","first-page":"197","volume-title":"Advances in Electrochemical Science and Engineering","author":"Buck M.","year":"2009"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0079-6816(00)00024-1"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0300789"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9502357"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.progsurf.2009.06.001"},{"key":"e_1_2_6_7_2","first-page":"39","author":"Vericat C.","year":"2010","journal-title":"Chem. 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