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In this context, the electrochemical properties of two different hole\u2010transporting materials (HTMs) and their chemical interactions with trioctylphosphine\u2010capped CdSe quantum dots are investigated to evaluate their potential use in hybrid quantum\u2010dot\u2010sensitized solar cells. Tris[4\u2010(thien\u20102\u2010yl)phenyl]amine (TTPA) and tris[4\u2010(selen\u20102\u2010yl)phenyl]amine (TSePA) are studied in the solid state as thin films deposited on a conducting substrate. Spectroelectrochemical studies evidence both solid\u2010state electropolymerization and doping. Upon addition of TSePA or partially polymerized TTPA to a colloidal solution of trioctylphosphine\u2010capped CdSe quantum dots, the steady\u2010state photoluminescence is quenched. This suggests that the quantum dots and the HTM strongly interact, probably through an excited\u2010state charge\u2010transfer mechanism. The combination of all these pieces of information indicates that polymerized TTPA and TSePA are potential candidates as HTMs for hybrid quantum\u2010dot\u2010sensitized solar cells.<\/jats:p>","DOI":"10.1002\/cphc.201001069","type":"journal-article","created":{"date-parts":[[2011,3,24]],"date-time":"2011-03-24T15:31:28Z","timestamp":1300980688000},"page":"1155-1164","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Characterization and Polymerization of Thienylphenyl and Selenylphenyl Amines and Their Interaction with CdSe Quantum Dots"],"prefix":"10.1002","volume":"12","author":[{"given":"Teresa","family":"Lana\u2010Villarreal","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Enrique","family":"Font\u2010Sanchis","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"\u00c1ngela","family":"Sastre\u2010Santos","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fernando","family":"Fern\u00e1ndez\u2010L\u00e1zaro","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roberto","family":"G\u00f3mez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2011,3,24]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/nn900756s"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2007.04.033"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050143"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/a908130e"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(20021016)14:20<1439::AID-ADMA1439>3.0.CO;2-H"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1386-9477(02)00374-0"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2009.10.016"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp020453l"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/pssb.200779546"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2009.06.049"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl902438d"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b911527g"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl101322h"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm0609045"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/0013-4686(95)00503-X"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma0202484"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma049404s"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2004.1266"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.3079399"},{"key":"e_1_2_6_20_2","doi-asserted-by":"crossref","unstructured":"H. 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