{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T15:51:33Z","timestamp":1785945093995,"version":"3.56.0"},"reference-count":55,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2013,10,14]],"date-time":"2013-10-14T00:00:00Z","timestamp":1381708800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2013,11,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Two optically active phthalocyanine derivatives with eight peripheral chiral (<jats:italic>S<\/jats:italic>)\u20104\u2032\u2010(2\u2010methylbutoxy)biphenyl moieties on the <jats:italic>\u03b2<\/jats:italic>\u2010position of the phthalocyanine ring are synthesized. The circular dichroism (CD) spectra show signals in the Q absorption region for both compounds <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> in chloroform solution, indicating the effective chiral\u2010information transfer from the peripheral chiral (<jats:italic>S<\/jats:italic>)\u20104\u2032\u2010(2\u2010methylbutoxy)biphenyl side chains to the phthalocyanine chromophore at the molecular level. Their self\u2010assembling properties are further investigated by using electronic absorption and Fourier transform infrared spectroscopy, transmission electronic microscopy, scanning electronic microscopy, X\u2010ray diffraction, and X\u2010ray photoelectron spectroscopy. Experimental results reveal the effect of the metal\u2010coordination bond on molecular packing models in these nanostructures, which in turn results in the self\u2010assembled nanostructures with different morphologies, from nanosheets for <jats:bold>1<\/jats:bold> to helical nanofibers for <jats:bold>2<\/jats:bold>. In addition, good semiconducting properties of the nanostructures fabricated from phthalocyanine derivatives <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> are revealed by current\u2013voltage measurements.<\/jats:p>","DOI":"10.1002\/cphc.201300604","type":"journal-article","created":{"date-parts":[[2013,10,14]],"date-time":"2013-10-14T09:33:01Z","timestamp":1381743181000},"page":"3827-3833","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Helical Self\u2010Assembly of Optically Active Phthalocyanine Derivatives: Effect of Zn\uf8ffO Coordination Bond on Morphology and Handedness of Nanostructures"],"prefix":"10.1002","volume":"14","author":[{"given":"Congcong","family":"Zhang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Jing","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sha","family":"Lin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zijuan","family":"Hao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Tian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaomei","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peihua","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2013,10,14]]},"reference":[{"key":"e_1_2_6_1_2","volume-title":"Phthalocyanine: Properties and Applications, Vol. 1\u20134","author":"Lever A. 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