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These very reactive compounds, which have to be removed from the reaction mixture as they are formed, were characterized by <jats:sup>1<\/jats:sup>H NMR and <jats:sup>13<\/jats:sup>C NMR spectroscopy. The IR spectra of <jats:italic>n<\/jats:italic>\u2010propyl\u2010, isopropyl\u2010, <jats:italic>n<\/jats:italic>\u2010butyl\u2010, and 3\u2010butenylmercury hydride were recorded for the first time. All compounds were then studied by density functional theory calculations on the basis of a recent theoretical assessment for alkylmercury compounds performed by our group. Comparison of the experimental and theoretical results allowed the assignment of the vibrational modes in an unambiguous way, in spite of the low intrinsic stability of some of the derivatives investigated. The experimental procedure implemented for registering the IR spectra of these unstable species in the gas phase allowed us to obtain reasonable estimates of their lifetimes.<\/jats:p>","DOI":"10.1002\/cphc.201300876","type":"journal-article","created":{"date-parts":[[2014,1,17]],"date-time":"2014-01-17T10:37:42Z","timestamp":1389955062000},"page":"530-541","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["On the Structures, Lifetimes, and Infrared Spectra of Alkylmercury Hydrides"],"prefix":"10.1002","volume":"15","author":[{"given":"Abdessamad","family":"Benidar","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M. 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