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SO<jats:sub>3<\/jats:sub>, SO<jats:sub>3<\/jats:sub><jats:sup>.\u2212<\/jats:sup> and SO<jats:sub>4<\/jats:sub><jats:sup>.\u2212<\/jats:sup> are efficiently produced by reaction of O<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>XO<jats:sup>\u2212<\/jats:sup> anions (X=Cl, Br, and I; <jats:italic>n<\/jats:italic>=0 and 1) with SO<jats:sub>2<\/jats:sub>; XO<jats:sup>\u2212<\/jats:sup> ions mainly react to give SO<jats:sub>3<\/jats:sub> by oxygen\u2010atom transfer, whereas OXO<jats:sup>\u2212<\/jats:sup> ions mainly give SO<jats:sub>3<\/jats:sub><jats:sup>.\u2212<\/jats:sup> by oxygen\u2010anion transfer. On descending the halogen group from chlorine to iodine, the SO<jats:sub>3<\/jats:sub>\/SO<jats:sub>3<\/jats:sub><jats:sup>.\u2212<\/jats:sup> ratio decreases and increases for reactions involving XO<jats:sup>\u2212<\/jats:sup> and OXO<jats:sup>\u2212<\/jats:sup> anions, respectively, whereas the formation of SO<jats:sub>4<\/jats:sub><jats:sup>.\u2212<\/jats:sup> is particularly significant with OIO<jats:sup>\u2212<\/jats:sup>. Kinetic factors play a major role in the reactions of O<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>XO<jats:sup>\u2212<\/jats:sup>, depending on the halogen atom and its oxidation state.<\/jats:p>","DOI":"10.1002\/cphc.201402306","type":"journal-article","created":{"date-parts":[[2014,6,20]],"date-time":"2014-06-20T10:51:03Z","timestamp":1403261463000},"page":"2723-2731","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["The Oxidation of Sulfur Dioxide by Single and Double Oxygen Transfer Paths"],"prefix":"10.1002","volume":"15","author":[{"given":"Anna","family":"Troiani","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marzio","family":"Rosi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chiara","family":"Salvitti","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Giulia","family":"de Petris","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,6,20]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","volume-title":"Chemistry of Atmospheres","author":"Wayne R. 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