{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T02:38:58Z","timestamp":1792031938752,"version":"4.4.0"},"reference-count":50,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2015,8,10]],"date-time":"2015-08-10T00:00:00Z","timestamp":1439164800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Science Foundation of China","doi-asserted-by":"crossref","award":["21406175"],"award-info":[{"award-number":["21406175"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"973 Programs of China","award":["2012CB619402"],"award-info":[{"award-number":["2012CB619402"]}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"crossref","award":["2013M542354"],"award-info":[{"award-number":["2013M542354"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2015,9,14]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We propose a series of azolium poly(azolyl)borate ionic liquids (ILs) for reversible SO<jats:sub>2<\/jats:sub> capture. Density functional calculations demonstrate that the designed borate anions can strongly bond to SO<jats:sub>2<\/jats:sub> at multiple sites with nearly uniform binding energies. Thus, as well as high overall uptakes, the ILs can achieve much higher effective uptakes (the uptake difference between absorption and desorption conditions) than existing SO<jats:sub>2<\/jats:sub>\u2010capture reagents. The larger size of the borate anions, the evenly distributed negative charge among the azolyl rings, and the blocking of the conjugation by the tetrahedral boron concertedly reduce absorbate\u2013absorbate repulsion, which leads to a large disparity among binding sites in other multiple\u2010site SO<jats:sub>2<\/jats:sub> sorbents.<\/jats:p>","DOI":"10.1002\/cphc.201500369","type":"journal-article","created":{"date-parts":[[2015,8,28]],"date-time":"2015-08-28T11:01:21Z","timestamp":1440759681000},"page":"2854-2860","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Multiple\u2010Site SO<sub>2<\/sub>\u2010Capture Ionic Liquids with Nearly Uniform Site Performance"],"prefix":"10.1002","volume":"16","author":[{"given":"Huarong","family":"Tang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongmei","family":"Lu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,8,10]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2010.03.023"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie051316o"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2509(00)00090-7"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1080\/10473289.2001.10464387"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/19887"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar7001649"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp311707e"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cp41769c"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie901254f"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz1014828"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200353437"},{"key":"e_1_2_6_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200353437"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja204808h"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201300224"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3GC41458B"},{"key":"e_1_2_6_15_2","unstructured":"Note: Instead of the more convenient conditions for measurements emphasized in most reports (at 20\u2009\u00b0C and 0.1 MPa of SO2) the harsher conditions (at 40\u2009\u00b0C and 0.01 MPa of SO2) are in line with the practical conditions of using IL to capture CO2. 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