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The low thermal stability of these highly boiling compounds leads to difficult studies in the gas phase where partial or complete decomposition is usually observed. Consequently, the reported physicochemical properties of such compounds in the gas phase are still scarce. Keeping with this, four simple cyanohydrins, the glycolonitrile and methyl, vinyl and ethynyl derivatives, have been selected. These are possible candidates for the Interstellar Medium, where the corresponding aldehydes and HCN have been detected, and could have played an important role in prebiotic chemistry, as already proposed for some of them. Three well\u2010suited spectroscopic techniques, namely, UV photoelectron, infrared, and Raman spectroscopies, in tandem with quantum calculations, have been chosen for the structure analysis. Photoelectron spectroscopy, successfully performed with gaseous compounds, provides the first comparative study on cyanohydrins in the gas phase.<\/jats:p>","DOI":"10.1002\/cphc.201500516","type":"journal-article","created":{"date-parts":[[2015,9,11]],"date-time":"2015-09-11T16:56:42Z","timestamp":1441990602000},"page":"3660-3671","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["The Electronic Structure of Some Cyanohydrins\u2014A\u2005Spectroscopically Under\u2010Investigated Family of Compounds"],"prefix":"10.1002","volume":"16","author":[{"given":"Anna","family":"Chrostowska","sequence":"first","affiliation":[{"name":"Universit\u00e9 de Pau et des Pays de l'Adour CNRS, UMR 5254-IPREM-Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Mat\u00e9riaux  2 avenue du Pr\u00e9sident Angot 64053 Pau France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Clovis","family":"Darrigan","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Pau et des Pays de l'Adour CNRS, UMR 5254-IPREM-Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Mat\u00e9riaux  2 avenue du Pr\u00e9sident Angot 64053 Pau France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alain","family":"Dargelos","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Pau et des Pays de l'Adour CNRS, UMR 5254-IPREM-Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Mat\u00e9riaux  2 avenue du Pr\u00e9sident Angot 64053 Pau France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Abdessamad","family":"Benidar","sequence":"additional","affiliation":[{"name":"Institut de Physique de Rennes UMR 6251 CNRS Universit\u00e9 de Rennes 1  Campus de Beaulieu 35042 Rennes Cedex France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jean\u2010Claude","family":"Guillemin","sequence":"additional","affiliation":[{"name":"Institut des Sciences Chimiques de Rennes Ecole Nationale Sup\u00e9rieure de Chimie de Rennes, CNRS, UMR 6226  11 All\u00e9e de Beaulieu, CS 50837 35708 Rennes Cedex 7 France"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,9,30]]},"reference":[{"key":"e_1_2_6_1_1","first-page":"81","volume-title":"Mechanism of Organic Reactions in the Interstellar Medium, in Astrobiology: Emergence, Search and Detection of Life","author":"Guillemin J.-C.","year":"2010"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1051\/0004-6361:20079203"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1051\/0004-6361\/201117602"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1051\/0004-6361\/201322371"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1088\/0004-637X\/756\/1\/11"},{"key":"e_1_2_6_6_1","first-page":"93","volume":"549","author":"Danger G.","year":"2013","journal-title":"Astrophys. 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