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Therefore, the present work seeks to understand the film growth mechanism of a model compound for potentially usable MPc, specifically, copper <jats:italic>tetra<\/jats:italic>(3\u2010nitro\u20105\u2010<jats:italic>tert<\/jats:italic>\u2010butyl)phthalocyanine (CuPc*). The Langmuir\u2010Schaefer (LS) technique was applied to prepare a series of CuPc* films under different processing conditions. The film growth was examined by Brewster angle microscopy (BAM) on the water surface and small\u2010angle X\u2010ray scattering (SAXS) from the solid films. Neutron reflectometry (NR) measurements of the water uptake into the films and computer simulation of hydrated CuPc* were performed to substantiate an idea of colloidal MPc\u2010water aggregates as nanoscale precursors of smooth solid films. This idea appears fruitful in terms of materials chemistry.<\/jats:p>","DOI":"10.1002\/cphc.201800956","type":"journal-article","created":{"date-parts":[[2018,12,12]],"date-time":"2018-12-12T04:09:49Z","timestamp":1544587789000},"page":"422-428","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Atypical Film\u2010Forming Behavior of Soluble Tetra\u20103\u2010Nitro\u2010Substituted Copper Phthalocyanine"],"prefix":"10.1002","volume":"20","author":[{"given":"Svetlana V.","family":"Zaitseva","sequence":"first","affiliation":[{"name":"G. A. Krestov Institute of Solution Chemistry Russian Academy of Science  1, Akademicheskaya St. 153045 Ivanovo Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Simona","family":"Bettini","sequence":"additional","affiliation":[{"name":"Department of Engineering for Innovation Campus University Ecotekne University of Salento  Via per Monteroni I-73100 Lecce Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ludovico","family":"Valli","sequence":"additional","affiliation":[{"name":"Department of Biological and Environmental Sciences and Technologies, DISTEBA University of Salento  Via per Arnesano I-73100 Lecce Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Arkadiy M.","family":"Kolker","sequence":"additional","affiliation":[{"name":"G. A. Krestov Institute of Solution Chemistry Russian Academy of Science  1, Akademicheskaya St. 153045 Ivanovo Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3392-4878","authenticated-orcid":false,"given":"Nicholas Y.","family":"Borovkov","sequence":"additional","affiliation":[{"name":"G. A. 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